Stereoselective Ketone Rearrangements with Hypervalent Iodine Reagents

Malmedy Florence; Wirth Thomas

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Stereoselective Ketone Rearrangements with Hypervalent Iodine Reagents

机译：高价碘试剂的立体选择性酮重排

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摘要

The first stereoselective version of an iodine(III)-mediated rearrangement of arylketones in the presence of orthoesters is described. The reaction products, alpha-arylated esters, are very useful intermediates in the synthesis of bio-active compounds such as ibuprofen. With chiral lactic acid-based iodine(III) reagents product selectivities of up to 73% ee have been achieved.

机译：描述了在原酸酯存在下碘（III）介导的芳基酮重排的第一个立体选择性形式。反应产物α-芳基化酯是生物活性化合物（如布洛芬）合成中非常有用的中间体。使用基于手性乳酸的碘（III）试剂，产品选择性高达73％ee。

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《Chemistry: A European journal》 |2016年第45期|共6页
作者
Malmedy Florence; Wirth Thomas;
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正文语种 eng
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关键词
addition; alkenes; iodine(III); rearrangement; stereoselective synthesis;

机译：加成;烯烃;碘（III）;重排;立体选择性合成;

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专利

1. Stereoselective Ketone Rearrangements with Hypervalent Iodine Reagents [J] . Malmedy Florence, Wirth Thomas Chemistry: A European journal . 2016,第45期

机译：高价碘试剂的立体选择性酮重排
2. Stereoselective Oxidative Rearrangement of Disubstituted Unactivated Alkenes Using Hypervalent Iodine(III) Reagent [J] . Pandey Chandra Bhan, Azaz Tazeen, Verma Ram Subhawan, The Journal of Organic Chemistry . 2020,第15期

机译：使用高效碘（III）试剂二取代的未活化烯烃的立体选择性氧化重排
3. Stereoselective Rearrangements with Chiral Hypervalent Iodine Reagents [J] . Umar Farid, Florence Malmedy, Romain Claveau Angewandte Chemie . 2013,第27期

机译：手性高价碘试剂的立体选择性重排
4. Synthesis of Sulfur-Containing Heterocycles Using A Hypervalent Iodine(III) Reagent [C] . Ling-Ching Chen International symposium for Chinese organic chemists . 2000

机译：使用高效碘（III）试剂合成含硫杂环
5. Towards the Synthesis of a Biphenyl Based Water-soluble Hypervalent Iodine Reagent to Probe Hypervalent Iodine Twist. [D] . Yeredla, Praveen Reddy. 2016

机译：寻求基于联苯的水溶性高价碘试剂的合成，以探测高价碘的扭曲。
6. Stereoselective Synthesis of 5-7 membered Cyclic Ethers by Deiodonative Ring-Enlargement Using Hypervalent Iodine Reagents [O] . Tomohito Abo, Masanori Sawaguchi, Hisanori Senboku, 2005

机译：使用高价碘试剂通过去碘环扩大立体选择性合成5-7元环醚
7. Frontispiece: stereoselective ketone rearrangements with hypervalent iodine reagents [O] . Malmedy Florence, Wirth Thomas 2016

机译：代表作：使用高价碘试剂的立体选择性酮重排

Stereoselective Ketone Rearrangements with Hypervalent Iodine Reagents

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