A Light/Ketone/Copper System for Carboxylation of Allylic C-H Bonds of Alkenes with CO2

Ishida Naoki; Masuda Yusuke; Uemoto Sho; Murakami Masahiro

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A Light/Ketone/Copper System for Carboxylation of Allylic C-H Bonds of Alkenes with CO2

机译：光/酮/铜体系用于烯烃与CO2的烯丙基C-H键的羧基化

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摘要

A photo-induced carboxylation reaction of allylic C-H bonds of simple alkenes with CO2 is prompted by means of a ketone and a copper complex. The unique carboxylation reaction proceeds through a sequence of an endergonic photoreaction of ketones with alkenes forming homoallyl alcohol intermediates and a thermal copper-catalyzed allyl transfer reaction from the homoallyl alcohols to CO2 through C-C bond cleavage.

机译：借助于酮和铜配合物促使简单烯烃的烯丙基C-H键与CO2发生光诱导的羧化反应。独特的羧化反应是通过酮与烯烃的高纯光反应序列形成高烯丙基醇中间体而进行的，以及通过C-C键裂解从高烯丙基醇向CO2进行热铜催化的烯丙基转移反应的过程。

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《Chemistry: A European journal》 |2016年第19期|共4页
作者
Ishida Naoki; Masuda Yusuke; Uemoto Sho; Murakami Masahiro;
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原文格式 PDF
正文语种 eng
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关键词
carbon dioxide; C-C activation; C-H activation; copper; synthetic method;

机译：二氧化碳;C-C活化;C-H活化;铜;合成方法;

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1. A Light/Ketone/Copper System for Carboxylation of Allylic C-H Bonds of Alkenes with CO2 [J] . Ishida Naoki, Masuda Yusuke, Uemoto Sho, Chemistry: A European journal . 2016,第19期

机译：光/酮/铜体系用于烯烃与CO2的烯丙基C-H键的羧基化
2. Carboxylation of Benzylic and Aliphatic C-H Bonds with CO_2 Induced by Light/Ketone/Nickel [J] . Naoki Ishida, Yusuke Masuda, Yuuya Imamura, Journal of the American Chemical Society . 2019,第50期

机译：光/酮/镍诱导的CO_2对苄基和脂肪族C-H键的羧基化
3. Copper-Catalyzed Trifluoromethylation of Terminal Alkenes through Allylic C-H Bond Activation [J] . Jun Xu, Yao Fu, Dong-Fen Luo, Journal of the American Chemical Society . 2011,第39期

机译：通过烯丙基C-H键活化，铜催化末端烯烃的三氟甲基化
4. A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Organoboronic Acid Esters:A New Method for C-C Bond Formation via C-H Bonds Cleavage [C] . Fumitoshi Kakiuchi, Shintaro Kan, Kimitaka Igi, Symposium on Organometallic Chemistry . 2003

机译：芳香酮与有机硼酸酯的芳香酮催化反应：通过C-H键切割的C-C键形成新方法
5. Copper-catalyzed functionalization of alkenes: Carboamination, C-H amination, C-H alkylation and carboetherifcation reactions. [D] . Liwosz, Timothy Walter. 2014

机译：铜催化烯烃的官能化：碳氨基化，C-H氨基化，C-H烷基化和碳醚化反应。
6. Cobalt-catalyzed nucleophilic addition of the allylic C(sp3)–H bond of simple alkenes to ketones [O] . Tsuyoshi Mita, Masashi Uchiyama, Kenichi Michigami, 2018

机译：钴催化简单烯基的烯丙基C（sp3）–H键的亲核加成反应
7. Carboxylation of Benzylic and Aliphatic CH Bonds with CO2 Induced by Light/Ketone/Nickel [O] . -1

机译：用光/酮/镍诱导CO 2的苄基和脂族CH键的羧化和脂族CH键

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A Light/Ketone/Copper System for Carboxylation of Allylic C-H Bonds of Alkenes with CO2

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