Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles

Li Wei-Huan; Wu Lin; Li Shuai-Shuai; Liu Chen-Fei; Zhang Guo-Tai; Dong Lin

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Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles

机译：铑催化的7-氮杂吲哚释放氢的正烯基化

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摘要

An efficient rhodium-catalyzed dehydrogenative Heck-type reaction between N-aryl-substituted 7-azaindoles and various alkenes through a H-2-releasing process without the need of any oxidizing agent was developed. The novel methodology broadens the scope of metal-catalyzed hydrogen-releasing reactions to include rhodium catalysis.

机译：开发了一种通过H-2释放过程在N-芳基取代的7-氮杂吲哚和各种烯烃之间进行有效的铑催化的脱氢Heck型反应，不需要任何氧化剂。该新方法拓宽了金属催化的氢释放反应的范围，使其包括铑催化。

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来源
《Chemistry: A European journal》 |2016年第50期|共5页
作者
Li Wei-Huan; Wu Lin; Li Shuai-Shuai; Liu Chen-Fei; Zhang Guo-Tai; Dong Lin;
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正文语种 eng
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关键词
7-azaindoles; hydrogen-releasing; olefin; ortho-alkenylation; rhodium;

机译：7-氮杂吲哚;氢释放;烯烃;正烯基化;铑;

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专利

1. Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles [J] . Li Wei-Huan, Wu Lin, Li Shuai-Shuai, Chemistry: A European journal . 2016,第50期

机译：铑催化的7-氮杂吲哚释放氢的正烯基化
2. Ruthenium- and Rhodium-Catalyzed Dehydrogenative ortho-Alkenylation of Benzylamines via Free Amino Group Directed C-H Bond Cleavage [J] . Chiharu Suzuki, Keisuke Morimoto, Koji Hirano Advanced synthesis & catalysis . 2014,第7期

机译：钌和铑催化的通过游离氨基基团直接进行C-H键裂解的苄胺的脱氢邻位烯基化
3. Rhodium-Catalyzed Tandem Annulation Reactions of 7-Azaindoles with Electron-Deficient Olefins via Double C-H Activation [J] . Li Shuai-Shuai, Lin Hui, Liu Chen-Fei, Advanced synthesis & catalysis . 2016,第10期

机译：铑通过双C-H活化催化7-氮杂吲哚与缺电子烯烃的串联环化反应
4. Hydrogen induced ductility loss of hydrogen-charged and hydrogen-releasing 304L austenitic stainless steel [C] . Yanfei Wang, Jianming Gong, Yong Jiang, International symposium on structural integrity . 2012

机译：氢致氢和释放氢的304L奥氏体不锈钢的氢致延展性损失
5. Synthesis and photoluminescent properties of starburst compounds based on 7-azaindole, indole and 3-methyl indole. [D] . Huang, Weihua. 2005

机译：基于7-氮杂吲哚，吲哚和3-甲基吲哚的星爆化合物的合成和光致发光性能。
6. Exploring 6-Azaindole and 7-Azaindole Rings for Developing Cannabinoid Receptor 1 Allosteric Modulators [O] . Sri Sujana Immadi, Rachel Dopart, Zhixing Wu, 2018

机译：探索6-氮杂吲哚和7-氮杂吲哚环以开发大麻素受体1变构调节剂。
7. Frontispiece: Rhodium-Catalyzed Hydrogen-Releasing ortho -Alkenylation of 7-Azaindoles [O] . Wei-Huan Li, Lin Wu, Shuai-Shuai Li, 2016

机译：正面：铑催化的氢释放邻邻 - 7-唑烷基化合物

Rhodium-Catalyzed Hydrogen-Releasing ortho-Alkenylation of 7-Azaindoles

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