Thioamination of Alkenes with Hypervalent Iodine Reagents

Mizar Pushpak; Niebuhr Rebecca; Hutchings Matthew; Farooq Umar; Wirth Thomas

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Thioamination of Alkenes with Hypervalent Iodine Reagents

机译：用高价碘试剂对烯烃进行硫胺化

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摘要

An efficient thioamination of alkenes mediated by iodine(III) reagents is described. The use of different sulfur nucleophiles allows the flexible synthesis of 1,2-aminothiols from alkenes. By employing chiral iodine(III) reagents, a stereoselective version of the thioamination protocol has also been developed.

机译：描述了由碘（III）试剂介导的烯烃的有效硫胺化。使用不同的硫亲核试剂可以从烯烃灵活地合成1,2-氨基硫醇。通过使用手性碘（III）试剂，还开发了硫代胺化方案的立体选择形式。

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来源
《Chemistry: A European journal》 |2016年第5期|共4页
作者
Mizar Pushpak; Niebuhr Rebecca; Hutchings Matthew; Farooq Umar; Wirth Thomas;
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正文语种 eng
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关键词
addition; alkenes; amination; heterocycles; iodine;

机译：加成;烯烃;胺化;杂环;碘;

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1. Thioamination of Alkenes with Hypervalent Iodine Reagents [J] . Mizar Pushpak, Niebuhr Rebecca, Hutchings Matthew, Chemistry: A European journal . 2016,第5期

机译：用高价碘试剂对烯烃进行硫胺化
2. Hypervalent Iodine-Mediated Alkene Functionalization: Oxazoline and Thiazoline Synthesis via Inter-/Intramolecular Aminohydroxylation and Thioamination [J] . Jeon Hyeonho, Kim Darong, Lee Ji Hoon, Advanced synthesis & catalysis . 2018,第4期

机译：高效碘介导的烯烃官能化：通过/分子内氨基羟基化和硫代聚酰胺的氧唑啉和噻唑啉合成
3. Hypervalent Iodine-Mediated Alkene Functionalization: Oxazoline and Thiazoline Synthesis via Inter-/Intramolecular Aminohydroxylation and Thioamination [J] . Jeon Hyeonho, Kim Darong, Lee Ji Hoon, Advanced synthesis & catalysis . 2018,第4期

机译：高效碘介导的烯烃官能化：通过/分子内氨基羟基化和硫代聚酰胺的氧唑啉和噻唑啉合成
4. Synthesis of Sulfur-Containing Heterocycles Using A Hypervalent Iodine(III) Reagent [C] . Ling-Ching Chen International symposium for Chinese organic chemists . 2000

机译：使用高效碘（III）试剂合成含硫杂环
5. Towards the Synthesis of a Biphenyl Based Water-soluble Hypervalent Iodine Reagent to Probe Hypervalent Iodine Twist. [D] . Yeredla, Praveen Reddy. 2016

机译：寻求基于联苯的水溶性高价碘试剂的合成，以探测高价碘的扭曲。
6. Thioamination of Alkenes with Hypervalent Iodine Reagents [O] . Dr. Pushpak Mizar, Rebecca Niebuhr, Matthew Hutchings, -1

机译：用高价碘试剂对烯烃进行硫胺化
7. Thioamination of alkenes with hypervalent iodine reagents [O] . Mizar, Pushpak, Niebuhr, Rebecca, Hutchings, Matthew, 2016

机译：用高价碘试剂对烯烃进行硫氨化

Thioamination of Alkenes with Hypervalent Iodine Reagents

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