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Polyelectrolyte Complexes Formed from Conjugated Polymers: Array-Based Sensing of Organic Acids

机译:由共轭聚合物形成的聚电解质复合物:基于阵列的有机酸感测

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摘要

One fluorescent, positively charged poly(para-phenyleneethynylene) (PAE1) forms electrostatic complexes with five negatively charged pyridine- or benzothiadiazole-containing poly(para-aryleneethynylene)s (PAE2-PAE6). The PAE2-PAE6 are less fluorescent in water and act as quenchers for PAE1 in their electrostatic complexes C1-C5; the PAE-complexes (2m) were exposed to thirteen different carboxylic acids (50mm) in buffered aqueous solution. The fluorescence responses of the small library of electrostatic PAE-complexes towards the acids was analyzed; discrimination of all of the thirteen acids was achieved. The investigated acids include acetic, butyric, tartaric, maleic, lactic, sorbic, oxalic, aspartic, and citric acids. A random, simple, ad-hoc library of electrostatic polymer complexes, C1-C5, therefore discerns the thirteen carboxylic acids in water.
机译:一种荧光的带正电荷的聚(对亚苯基乙炔基)(PAE1)与五个带负电荷的含吡啶或苯并噻二唑的聚(对亚芳基乙炔基)(PAE2-PAE6)形成静电配合物。 PAE2-PAE6在水中的荧光较小,并在其静电配合物C1-C5中充当PAE1的猝灭剂;将PAE复合物(2m)暴露于缓冲水溶液中的13种不同的羧酸(50mm)中。分析了小型静电PAE复合物库对酸的荧光响应;区分了所有十三种酸。研究的酸包括乙酸,丁酸,酒石酸,马来酸,乳酸,山梨酸,草酸,天冬氨酸和柠檬酸。因此,一个随机,简单,特殊的静电聚合物配合物库C1-C5识别出水中的13种羧酸。

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