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首页> 外文期刊>Chemical Physics Letters >Greatly enhanced and controlled manganese photoluminescence in water-soluble ZnCdS:Mn/ZnS core/shell quantum dots
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Greatly enhanced and controlled manganese photoluminescence in water-soluble ZnCdS:Mn/ZnS core/shell quantum dots

机译:在水溶性ZnCdS:Mn / ZnS核/壳量子点中大大增强和控制了锰的光致发光

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摘要

Stable and water-soluble ZnCdS:Mn/ZnS core/shell quantum dots (QDs) with quantum yields over 20% have been synthesized via a one-spot aqueous route. Compared with the ZnCdS:Mn cores, the ZnCdS: Mn/ZnS core/shell QDs exhibited approximately 21.0 times stronger photoluminescence due to the greatly decreased nonradiative decay rate. A corresponding synthetic mechanism for such enhancement is discussed in detail. Furthermore, the bandgap energy of the ZnCdS: Mn/ZnS QDs is tuned to a lower level by increasing the Cd concentration in the cores, and the applicability for preparing QD-LEDs with high lumen efficiency is also described.
机译:通过单点水途径合成了量子产率超过20%的稳定且水溶性的ZnCdS:Mn / ZnS核/壳量子点(QDs)。与ZnCdS:Mn核相比,ZnCdS:Mn / ZnS核/壳量子点由于非辐射衰减率大大降低,因此表现出的光致发光强度约为21.0倍。详细讨论了用于这种增强的相应合成机制。此外,通过增加芯中的Cd浓度,将ZnCdS:Mn / ZnS QD的带隙能量调节到较低的水平,并且还描述了制备具有高流明效率的QD-LED的适用性。

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