Plasmachemical Double Click Thiol-ene Reactions for Wet Electrical Barrier

Fraser R. C.; Carletto A.; Wilson M.; Badyal J. P. S.

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Plasmachemical Double Click Thiol-ene Reactions for Wet Electrical Barrier

机译：用于湿电势垒的等离子体化学双击硫醇反应

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Click thiol-ene chemistry is demonstrated for the reaction of thiol containing molecules with surface alkene bonds during electrical discharge activation. This plasmachemical reaction mechanism is shown to be 2-fold for allyl mercaptan (an alkene and thiol group containing precursor), comprising self-cross-linked nanolayer deposition in tandem with interfacial cross-linking to the surface alkene bonds of a polyisoprene base layer. A synergistic multilayer structure is attained which displays high wet electrical barrier performance during immersion in water.

机译：在放电活化过程中，点击硫醇-烯化学证明了含硫醇分子与表面烯烃键的反应。对于烯丙基硫醇（含烯烃和硫醇基团的前体），该等离子体化学反应机理显示为2倍，包括与聚异戊二烯基础层的表面烯烃键进行界面交联的自交联纳米层沉积。获得了一种协同的多层结构，该结构在浸入水中时显示出高的湿电阻挡性能。

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《ACS applied materials & interfaces》 |2016年第33期|共7页
作者
Fraser R. C.; Carletto A.; Wilson M.; Badyal J. P. S.;
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正文语种 eng
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plasmachemical deposition; thiol-ene click reaction; wet electrical barrier; multilayer; electronics;

机译：等离子体化学沉积;硫醇-烯点击反应;湿电势垒;多层;电子学;

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1. Plasmachemical Double Click Thiol-ene Reactions for Wet Electrical Barrier [J] . Fraser R. C., Carletto A., Wilson M., ACS applied materials & interfaces . 2016,第33期

机译：用于湿电势垒的等离子体化学双击硫醇反应
2. Heterofunctionalized Multiarm Star Polymers via Sequential Thiol-para-Fluoro and Thiol-Ene Double "Click" Reactions [J] . Cakir Nese, Tunca Umit, Hizal Gurkan, Macromolecular chemistry and physics . 2016,第5期

机译：通过顺序的巯基-对氟和硫醇-烯双“点击”反应进行杂官能化的多臂星形聚合物
3. Selective Cell Adhesion and Biosensing Applications of Bio-Active Block Copolymers Prepared by CuAAC/Thiol-ene Double Click Reactions [J] . Eyrilmez Gizem Oyman, Doran Sean, Murtezi Eljesa, Macromolecular bioscience . 2015,第9期

机译：CuAAC /硫醇-烯双击反应制备的生物活性嵌段共聚物的选择性细胞粘附和生物传感应用
4. Multiphoton Fabrication of Protein Hydrogels in 3-dimensions via Thiol-ene Photo-click Reactions [C] . Xiao-hua Qin, Jan Torgerson, Andreas Mautner, World biomaterials congress . 2012

机译：硫醇-烯光点击反应在三维中蛋白质水凝胶的多光子制备
5. Controlling Chemical Modification of Chlorinated Silicon Surfaces Via Wet-Chemistry Approaches and Morphology-Preserving Functionalization of Metal Oxide Nanomaterials Through Two-Step Click Reaction [D] . ?He, Chuan 2020

机译：通过两步咔哒反应控制通过湿化化学方法和金属氧化物纳米材料的形态保护官能化的化学改性。通过两步咔哒反应
6. Joint-Linker Type Ionic Gels Using Polymerizable Ionic Liquid as a Crosslinker via Thiol-Ene Click Reactions [O] . Kumkum Ahmed, Aoi Inagaki, Naofumi Naga 2020

机译：通过硫醇-ENE咔哒反应使用可聚合离子液体作为交联剂的关节接头式离子凝胶
7. Plasmachemical double click thiol–ene reactions for wet electrical barrier. [O] . Fraser R. C., Carletto A., Wilson M., 2016

机译：等离子体化学双击硫醇-烯反应可实现湿式电子屏障。

Plasmachemical Double Click Thiol-ene Reactions for Wet Electrical Barrier

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