Can methylene amidogene and its isomers be formed by a concerted reaction?

Metropoulos A.

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Can methylene amidogene and its isomers be formed by a concerted reaction?

机译：亚甲基酰胺基因及其异构体可以通过协同反应形成吗？

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We have explored the possibility of occurrence of the concerted formation of the methylene amidogene radical and its cis isomer from H_2 and CN at energy regimes of over 60 kcal/mol relative to the ground state of the radical. We have concluded that for the cases of parallel and perpendicular orientations of H_2 and CN, a concerted reaction is possible in principle provided that H_2 is vibrationally excited.

机译：我们已经探索了在相对于基团基态超过60 kcal / mol的能量状态下，由H_2和CN协同形成亚甲基酰胺基自由基及其顺式异构体的可能性。我们得出的结论是，对于H_2和CN平行和垂直取向的情况，只要H_2被振动激发，原则上就可以采取协调一致的反应。

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《International Journal of Quantum Chemistry》 |2011年第3期|共7页
作者
Metropoulos A.;
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正文语种 eng
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concerted reactions; high energy; methylene amidogene;

机译：协同反应;高能;亚甲基酰胺基;

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1. Can methylene amidogene and its isomers be formed by a concerted reaction? [J] . Metropoulos A. International Journal of Quantum Chemistry . 2011,第3期

机译：亚甲基酰胺基因及其异构体可以通过协同反应形成吗？
2. Concertedness and solvent effects in multiple proton transfer reactions: The formic acid dimer in solution [J] . Kohanoff J., Estrin DA., Laria D., The Journal of Chemical Physics . 2000,第21期

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3. A concerted SCF-MO ab initio and vibrational spectroscopic study of the conformational isomerism in 2-aminoethanol [J] . Constanca F. P. Silva, Maria Leonor T. S. Duarte, Rui Fausto Journal of Molecular Structure . 1999,第0期

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7. Mechanism of the color reaction of active methylene compounds with 1,3,5-trinitrobenzene derivatives. X. Three isomers of 1:2 complex of picric acid and creatinine. [O] . KAZUYA KOHASHI, YASUTO TSURUTA, YOSUKE OHKURA 1978

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8. Methyl guanine isomer differentiation using ion/molecule reactions and collision activated dissociation in a Fourier transform mass spectrometer [R] . Nourse, B D, Hettich, R L, Buchanan, M V 1992

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Can methylene amidogene and its isomers be formed by a concerted reaction?

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