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Facile one-pot synthesis of near-infrared luminescent gold nanoparticles for sensing copper (II)

机译:方便的一锅法合成用于感测铜的近红外发光金纳米粒子(II)

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Novel near-infrared luminescent gold nanoparticles (NIRL-AuNPs) were synthesized by a simple, rapid and one-pot procedure. The driving force for the formation of these NIRL-AuNPs was attributed to the heat-assisted reduction of a gold(I)-thiol complex. These gold nanoparticles were characterized by TEM, DLS, FT-IR and XPS. Luminescence studies indicated that these NIRL-AuNPs exhibited strong emission with peak maximum at 810 nm, microsecond-range photoluminescence lifetime, large Stokes shifts (>400 nm) and stabilities towards photobleaching and chemical oxidation. The sensing application for Cu2+ ions of these NIRL-AuNPs was demonstrated. These as-synthesized gold nanoparticles will provide a new NIRL nanomaterial for in vitro and in vivo applications.
机译:通过简单,快速和一锅法合成了新型近红外发光金纳米粒子(NIRL-AuNPs)。这些NIRL-AuNPs形成的驱动力归因于金(I)-硫醇络合物的热辅助还原。这些金纳米颗粒通过TEM,DLS,FT-IR和XPS表征。发光研究表明,这些NIRL-AuNPs表现出强发光,在810 nm处具有最大峰值,微秒范围的光致发光寿命,较大的斯托克斯位移(> 400 nm)以及对光漂白和化学氧化的稳定性。演示了这些NIRL-AuNPs对Cu2 +离子的传感应用。这些合成的金纳米颗粒将为体外和体内应用提供一种新的NIRL纳米材料。

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