Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides

Yu Xiaoli; Wu Qiujin; Wan Huida; Xu Zhaojun; Xu Xingle; Wang Dawei

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Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides

机译：铜和三苯基膦促进的芳基磺酰氯对醌的亚磺酰基化

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The efficient copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides has been developed under mild conditions with moderate to good yields. Significantly, this provides an alternative method to synthesise arylthioquinone derivatives. This is the first time that arylthioquinones with arylsulfonyl chlorides as starting material have been prepared, which avoids the use of the awful smelling thioalcohols and thiophenols.

机译：已经在温和的条件下以中等到良好的产率开发了用芳基磺酰氯对铜进行有效的铜和三苯膦促进的亚砜基化。重要的是，这提供了另一种合成芳基硫醌衍生物的方法。这是第一次制备以芳基磺酰氯为原料的芳基硫醌，避免了使用难闻的硫醇和硫酚。

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《RSC Advances》 |2016年第67期|共4页
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Yu Xiaoli; Wu Qiujin; Wan Huida; Xu Zhaojun; Xu Xingle; Wang Dawei;
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1. Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides [J] . Yu Xiaoli, Wu Qiujin, Wan Huida, RSC Advances . 2016,第67期

机译：铜和三苯基膦促进的芳基磺酰氯对醌的亚磺酰基化
2. Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides [J] . Xiaoli Yu, Qiujin Wu, Huida Wan, RSC Advances . 2016,第67期

机译：用芳基磺酰氯促进醌醌的铜膦酰基化醌
3. Copper-Catalyzed Regioselective Sulfenylation of Indoles with Arylsulfonyl Chlorides [J] . Wu Zhimeng, Li Yan-Chun, Ding Wen-Zhang, Asian Journal of Organic Chemistry . 2016,第5期

机译：铜催化的芳基磺酰氯对吲哚的区域选择性亚磺酰基化
4. Copper-Catalyzed Sulfenylation of Alkenes Using Thiols [C] . Nobukazu Taniguchi 日本化学会春季年会講演予稿集 . 2018

机译：使用硫醇铜催化烯烃的磺酰化
5. Kinetics and Transport Phenomena in the Chemical Decomposition of Copper Oxychloride in the Thermochemical Copper Chloride Cycle. [D] . Marin, Gabriel D. 2012

机译：氯化铜热化学循环中三氯氧化铜化学分解的动力学和输运现象。
6. General scheme of the phosphotriester condensation in the oligodeoxyribonucleotide synthesis with arylsulfonyl chlorides and arylsulfonyl azolides. [O] . V F Zarytova, D G Knorre 1984

机译：寡脱氧核糖核苷酸与芳基磺酰氯和芳基磺酰偶氮化物合成中的磷酸三酯缩合的一般流程。
7. A copper-induced quinone degradation pathway provides protection against combined copper/quinone stress in Lactococcus lactis IL1403. [O] . Mancini Stefano, Abicht Helge, Gonskikh Yulia, 2015

机译：铜诱导的醌降解途径为乳酸乳球菌IL1403中的铜/醌组合应力提供了保护。
8. The Interaction of Hydrazine with Copper(II) Chloride in Acidic Solutions. The Formation, Spectral and Magnetic Properties, and Structures of Copper(II), Copper(I), and Mixed Valence Species. [R] . Brown, D. B., Donner, J. A., Hall, J. W., 1979

机译：肼与氯化铜（II）在酸性溶液中的相互作用。铜（II），铜（I）和混合价物种的形成，光谱和磁性以及结构。

Copper and triphenylphosphine-promoted sulfenylation of quinones with arylsulfonyl chlorides

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