Palladium-copper catalyzed C(sp(3))-C(sp(2)) bond C-H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9H-xanthene and 9,9-diaryl-xanthene derivatives

Shen Guodong; Zhao Lingyu; Wang Yichen; Xia Wenfang; Yang Mingsen; Zhang Tongxin

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Palladium-copper catalyzed C(sp(3))-C(sp(2)) bond C-H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9H-xanthene and 9,9-diaryl-xanthene derivatives

机译：钯-铜催化的C（sp（3））-C（sp（2））键C-H活化交叉偶联反应：选择性芳基化反应合成9-芳基-9H-x吨和9,9-二芳基-吨衍生物

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A novel cooperatively catalyzed C(sp(3))-C(sp(2)) bond C-H activation cross-coupling reaction has been developed. A series of 9-aryl-9H-xanthenes and 9,9-diaryl-xanthenes were selectively synthesized in moderate to good yields by controlling the reaction time and temperature.

机译：一种新型的合作催化的C（sp（3））-C（sp（2））键C-H活化交叉偶联反应已经开发出来。通过控制反应时间和温度，以中等至良好的产率选择性地合成了一系列9-芳基-9H-黄嘌呤和9,9-二芳基-黄嘌呤。

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《RSC Advances》 |2016年第88期|共4页
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Shen Guodong; Zhao Lingyu; Wang Yichen; Xia Wenfang; Yang Mingsen; Zhang Tongxin;
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1. Palladium-copper catalyzed C(sp(3))-C(sp(2)) bond C-H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9H-xanthene and 9,9-diaryl-xanthene derivatives [J] . Shen Guodong, Zhao Lingyu, Wang Yichen, RSC Advances . 2016,第88期

机译：钯-铜催化的C（sp（3））-C（sp（2））键C-H活化交叉偶联反应：选择性芳基化反应合成9-芳基-9H-x吨和9,9-二芳基-吨衍生物
2. Palladium-copper catalyzed C(sp(3))-C(sp(2)) bond C-H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9H-xanthene and 9,9-diaryl-xanthene derivatives [J] . Shen Guodong, Zhao Lingyu, Wang Yichen, RSC Advances . 2016,第88期

机译：钯-铜催化的C（sp（3））-C（sp（2））键C-H活化交叉偶联反应：选择性芳基化反应合成9-芳基-9H-x吨和9,9-二芳基-吨衍生物
3. Palladium–copper catalyzed C(sp3)–C(sp2) bond C–H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9H-xanthene and 9,9-diaryl-xanthene derivatives [J] . Guodong Shen, Lingyu Zhao, Yichen Wang, RSC Advances . 2016,第88期

机译：钯 - 铜催化C（SP3）-C（SP2）键合C-H激活交叉偶联反应：选择性芳基合成9-芳基-9H- X吨和9,9-二芳基 - x吨衍生物
4. Palladium-catalyzed Selective Arylation of Azulenes at the1,3-Positions based on the C-H Activation by Utilizing 2-PyridylSubstituent as a Directing group [C] . Takuya Nagasawa, Yoshihiro Ogasawara, Tomoaki Yatsu 日本化学会春季年会 . 2020

机译：通过利用2-吡啶基取代剂作为指导基团，基于C-H激活在1,3-位蛋白催化紫红素的选择性浓缩
5. Palladium-mediated carbon-carbon bond formation: Methodology and mechanism. Part I: Palladium-catalyzed alpha-arylation of aryl nitromethanes, phosphonoacetates, and phosphine oxides. Part II: Mechanistic study of the palladium-mediated chemoselective activation of C(sp3)-H bonds. [D] . VanGelder, Kelsey Faith. 2016

机译：钯介导的碳-碳键形成：方法和机理。第一部分：芳族硝基甲烷，膦酰基乙酸酯和氧化膦的钯催化α-芳基化反应。第二部分：钯介导的C（sp3）-H键的化学选择性激活的机理研究。
6. Scope and Limitations of Auxiliary-Assisted Palladium-Catalyzed Arylation and Alkylation of sp2 and sp3 C-H Bonds [O] . Enrico T. Nadres, Gerson Ivan Franco Santos, Dmitry Shabashov, -1

机译：sp2和sp3 C-H键的辅助钯催化的芳基化和烷基化的范围和限制
7. Highly Efficient Copper-Catalyzed Nitro-Mannich Type Reaction: Cross-Dehydrogenative-Coupling between sp3 C-H Bond and sp3 C-H Bond [O] . -1

机译：高效铜催化的硝基 - 曼尼奇型反应：SP3 C-H键和SP3 C-H键之间的交叉脱氢偶联

Palladium-copper catalyzed C(sp(3))-C(sp(2)) bond C-H activation cross-coupling reaction: selective arylation to synthesize 9-aryl-9H-xanthene and 9,9-diaryl-xanthene derivatives

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