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Efficient near-infrared luminescence and energy transfer in erbium/bismuth codoped zeolites

机译://铋共掺杂沸石中的高效近红外发光和能量转移

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摘要

We have shown that tunable and highly efficient broadband near-IR (NIR) luminescence can be realized in erbium/bismuth codoped zeolites. The emission covers the ranges of 930-1450 nm and 1450-1630 nm. The intensity ratio of the two bands can be tuned by adjusting the concentration of erbium and the excitation wavelength. Steady-state and time-resolved photoluminescence (PL), and PL excitation measurements indicate that two kinds of emitters coexist in the pores of zeolites, and that NIR active bismuth simultaneously acts as a sensitizer of erbium. The present results demonstrate an important rational strategy for the design of a tunable NIR-emitting zeolite-based nanosystem.
机译:我们已经表明,在掺有//铋的沸石中可以实现可调谐且高效的宽带近红外(NIR)发光。发射范围为930-1450 nm和1450-1630 nm。可以通过调节的浓度和激发波长来调节两个波段的强度比。稳态和时间分辨光致发光(PL)以及PL激发测量表明,两种发射体共存于沸石的孔中,并且NIR活性铋同时充当as的敏化剂。目前的结果证明了一种重要的合理策略,用于设计可调谐NIR发射沸石基纳米系统。

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