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Porphyrin-doped solgel-lined structured optical fibers for local and remote sensing

机译:掺有卟啉的溶胶凝胶衬里结构化光纤,用于本地和遥感

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摘要

We constructed a type of sensor by depositing a solgel layer within the interior holes of a silica-structured fiber and, subsequently, coating this with an acid-responsive porphyrin. Protonation of the porphyrin by an acidic gas (HCl in this case), is detected by a large change in the visible spectrum. Compared to previous work on a liquid-core sensor in a structured optical fiber, the signal-to-noise ratio of this gas sensor shows a reduced signal strength, but the detection rate is increased about fortyfold.
机译:我们通过在二氧化硅结构纤维的内部孔中沉积溶胶凝胶层,然后用酸响应性卟啉涂层该传感器来构造一种传感器。通过可见光谱的大变化可以检测到卟啉被酸性气体(在这种情况下为HCl)质子化。与先前在结构化光纤中对液芯传感器进行的工作相比,该气体传感器的信噪比显示出降低的信号强度,但检测率却提高了约40倍。

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