Gold-Catalyzed Cycloisomerization and Diels-Alder Reaction of 1,6-Diyne Esters with Alkenes and Diazenes to Hydronaphthalenes and -cinnolines

Yan Jianming; Tay Guan Liang; Neo Cuien; Lee Bo Ra; Chan Philip Wai Hong

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Gold-Catalyzed Cycloisomerization and Diels-Alder Reaction of 1,6-Diyne Esters with Alkenes and Diazenes to Hydronaphthalenes and -cinnolines

机译：金催化的环烯异构化反应以及1,6-二炔酯与烯烃和二烯的Diels-Alder反应生成氢化萘和-肉桂醛

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A method for the efficient preparation of hydronaphthalene and -cinnoline derivatives by Au(I)-catalyzed cydoisomerzation of 1,6-diyne esters followed by a Diels-Alder reaction with alkenes or diazenes under mild conditions at room temperature with catalyst loadings as low as 1 mol % is described.

机译：一种通过Au（I）催化的1,6-二炔酯的环十二烷基异构化反应，然后在温和的条件下，室温下以低至催化剂负载量与烯烃或二氮烯进行Diels-Alder反应的有效制备氢化萘和-辛啉衍生物的方法描述了1mol％。

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《Organic letters》 |2015年第17期|共4页
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Yan Jianming; Tay Guan Liang; Neo Cuien; Lee Bo Ra; Chan Philip Wai Hong;
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1. Gold-Catalyzed Cycloisomerization and Diels-Alder Reaction of 1,6-Diyne Esters with Alkenes and Diazenes to Hydronaphthalenes and -cinnolines [J] . Yan Jianming, Tay Guan Liang, Neo Cuien, Organic letters . 2015,第17期

机译：金催化的环烯异构化反应以及1,6-二炔酯与烯烃和二烯的Diels-Alder反应生成氢化萘和-肉桂醛
2. Gold-Catalyzed Cycloisomerization of 1,6-Diyne Carbonates and Esters to 2,4a-Dihydro-1H-fluorenes [J] . Weidong Rao, Ming Joo Koh, Dan Li, Journal of the American Chemical Society . 2013,第21期

机译：金催化的1,6-二炔碳酸酯和酯的环异构化成2,4a-二氢-1H-芴
3. Gold-Catalyzed Cycloisomerization and Diels-Alder Reaction of 1,4,9-Dienyne Esters to 3a,6-Methanoisoindole Esters with Pro-Inflammatory Cytokine Antagonist Activity [J] . Susanti Dewi, Liu Li-Juan, Rao Weidong, Chemistry: A European journal . 2015,第25期

机译：金催化环化和1,4,9-二烯炔酯与具有促炎性细胞因子拮抗活性的3a，6-甲基异吲哚酯的Diels-Alder反应
4. Mechanism of Gold-Catalyzed Cycloisomerization of Enynyl Esters [C] . Andrea Correa, Luigi Cavallo NATO Advanced Study Institute on Green Metathesis Chemistry: Great Challenges in Synthesis, Catalysis and Nanotechnology . 2010

机译：烯基酯的金催化环素化机理
5. Halocyclizations and cycloisomerizations of 1,6-diynes, and sequence-defined, self-replicating polymers. [D] . Strom, Kyle Robert. 2017

机译：1,6-二炔和序列定义的自复制聚合物的卤环化和环异构化。
6. Gold-Catalyzed Diastereoselective Cycloisomerization of Alkylidene Cyclopropane Bearing 16-Diynes [O] . Dr. Hongchao Zheng, Laura L. Adduci, Dr. Ryan J. Felix, -1

机译：金催化的含16-二炔的亚炔基环丙烷的非对映选择性环异构化
7. Gold-catalyzed cycloisomerization and Diels-Alder reaction of 1,4,9-Dienyne Esters to 3 a,6-Methanoisoindole Esters with pro-inflammatory cytokine antagonist activity [O] . Susanti Dewi, Liu Li-Juan, Rao Weidong, 2015

机译：金催化环异构化和1,4,9-二烯炔酯与具有促炎性细胞因子拮抗剂活性的3 a，6-甲基异吲哚酯的Diels-Alder反应

Gold-Catalyzed Cycloisomerization and Diels-Alder Reaction of 1,6-Diyne Esters with Alkenes and Diazenes to Hydronaphthalenes and -cinnolines

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