Oxidative Addition of Glycosylbromides to trans-Ir(PMe3)(2)(CO)Cl

Pelczar EM; Munro-Leighton C; Gagne MR

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Oxidative Addition of Glycosylbromides to trans-Ir(PMe3)(2)(CO)Cl

机译：糖基溴化物向反式Ir（PMe3）（2）（CO）Cl的氧化加成

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trans-Ir(PMe3)(2)(CO)Cl reacts with acetobromo-alpha-D-glucose in the presence of AIBN to give a 1.3:1 ratio of the retentive and invertive oxidative addition products, each of which were characterized by crystallography. Reaction with (X-D-glucopyranosyl bromide tetrabenzoate gave a 2:1 alpha:beta ratio, while acetobromo-alpha-D-mannose gave a 5:1 ratio of retentive to invertive products.

机译：在AIBN存在下，反式-Ir（PMe3）（2）（CO）Cl与乙酰溴-α-D-葡萄糖反应，得到1.3：1的保持性和反向氧化加成产物比例，每种均通过晶体学表征。与（X-D-吡喃葡萄糖基溴化四苯甲酸酯）的反应产生2：1的α：β比率，而乙酰溴-α-D-甘露糖的保留产物与反相产物的比率为5：1。

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来源
《Organometallics》 |2009年第3期|共3页
作者
Pelczar EM; Munro-Leighton C; Gagne MR;
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正文语种 eng
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VALENT METAL-COMPLEXES; C-GLYCOSIDES; ALKYL-HALIDES; CARBON; IRIDIUM(I); RADICALS;

机译：价金属络合物;C-糖苷;烷基卤化物;碳;铱（I）;自由基;

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Oxidative Addition of Glycosylbromides to trans-Ir(PMe3)(2)(CO)Cl

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