Synthesis and catalytic activity of [Cp′Co(COD)] complexes bearing pendant N-containing groups

Thiel I.; Lama? M.; Jiao H.; Spannenberg A.; Hapke M.

首页> 外文期刊>Organometallics >Synthesis and catalytic activity of [Cp′Co(COD)] complexes bearing pendant N-containing groups

【24h】

Synthesis and catalytic activity of [Cp′Co(COD)] complexes bearing pendant N-containing groups

机译：含侧基含氮基团的[Cp'Co（COD）]配合物的合成和催化活性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The novel Co(I)-complex [Cp~(CN)Co(COD)] (Cp~(CN) = η~5-(C_5H_4CMe_2CH_2CN), COD = 1,5-cyclooctadiene; 3) with a substituted cyclopentadienyl ligand containing a pendant nitrile moiety has been synthesized and characterized by X-ray diffraction. The reactivity of the nitrile group in 3 has been investigated regarding its behavior in cyclization reactions with alkynes, leading to three new complexes containing pendant 2-pyridyl groups. All synthesized complexes have been evaluated as catalysts in the [2 + 2 + 2] cycloaddition reaction of 1,6-heptadiyne and benzonitrile.

机译：具有取代环戊二烯基配体的新型Co（I）络合物[Cp〜（CN）Co（COD）]（Cp〜（CN）=η〜5-（C_5H_4CMe_2CH_2CN），COD = 1,5-环辛二烯; 3）合成了侧基腈部分，并通过X射线衍射对其进行了表征。已经研究了3中腈基在与炔烃的环化反应中的反应性，从而产生了三个新的含2-吡啶基侧基的配合物。所有合成的配合物均已作为1,6-庚二炔和苄腈的[2 + 2 + 2]环加成反应的催化剂进行了评估。

著录项

来源
《Organometallics》 |2013年第11期|共4页
作者
Thiel I.; Lama? M.; Jiao H.; Spannenberg A.; Hapke M.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Synthesis; catalytic activity; complexes;

机译：合成;催化活性;配合物;

相似文献

外文文献
中文文献
专利

1. Synthesis and catalytic activity of [Cp′Co(COD)] complexes bearing pendant N-containing groups [J] . Thiel I., Lama? M., Jiao H., Organometallics . 2013,第11期

机译：含侧基含氮基团的[Cp'Co（COD）]配合物的合成和催化活性
2. Synthesis of new iridium N-heterocyclic carbene complexes bearing a functionalized Cp* ligand and their high catalytic activities in the Oppenauer-type oxidation of alcohol [J] . Hanasaka F, Fujita K, Yamaguchi R Organometallics . 2006,第19期

机译：带有官能化Cp *配体的新型铱N-杂环卡宾配合物的合成及其在醇的Oppenauer型氧化中的高催化活性
3. Indenyl-Nickel Complexes Bearing a Pendant,Hemilabile Olefin Ligand:Preparation,Characterization,and Catalytic Activities [J] . Daniel Gareau, Christine Sui-Seng, Laurent F.Groux, Organometallics . 2005,第16期

机译：带有悬垂物，半不稳定烯烃配体的茚基-镍配合物：制备，表征和催化活性
4. Synthesis,Structure and Catalytic Activity of Cp*Ir Carbene Complexes [C] . Fumihiro Hanasaka, Ken-ichi Fujita, Ryohei Yamaguchi Symposium on Organometallic Chemistry . 2003

机译：CP * IR Carbene复合物的合成，结构和催化活性
5. Copper complexes bearing pendant, protonatable noncoordinating groups: Synthesis, structural characterization and DNA cleavage activity. [D] . Villanueva, Nydia D. 1998

机译：带有侧基，可质子化的非配位基团的铜配合物：合成，结构表征和DNA裂解活性。
6. Synthesis Reactivity and Catalytic Transfer HydrogenationActivity of Ruthenium Complexes Bearing NNN Tridentate Ligands: Influenceof the Secondary Coordination Sphere [O] . Jing Shi, Bowen Hu, Xiangyang Chen, 2017

机译：合成反应性和催化转移加氢带有NNN三齿配体的钌配合物的活性：影响二级协调领域
7. Synthesis of New Iridium N-Heterocyclic Carbene Complexes Bearing a Functionalized Cp* Ligand and Their High Catalytic Activities in the Oppenauer-Type Oxidation of Alcohol [O] . -1

机译：含有官能化CP *配体的新型铱N-杂环卡宾络合物的合成及其在醇型氧化中的高催化活性

Synthesis and catalytic activity of [Cp′Co(COD)] complexes bearing pendant N-containing groups

摘要

著录项

相似文献

相关主题

期刊订阅