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Effect of solutes on the heterogeneous nucleation temperature of supercooled water: an experimental determination

机译:溶质对过冷水非均相成核温度的影响:实验确定

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We investigate the effect of solute concentration on the heterogeneous ice nucleation temperature (T_(het)) of aqueous solutions of both NaCl and D-glucose. An automatic lag time apparatus (ALTA) technique allows the dependence of T_(het) on solute concentration to be determined with statistical significance. Our results point to the solute-induced lowering of T_(het) being a factor of two times the equivalent melting point depression at any fixed concentration, the same factor reported for homogeneous nucleation experiments with small molecular weight solutes.
机译:我们研究了溶质浓度对NaCl和D-葡萄糖水溶液的非均相冰成核温度(T_(het))的影响。自动滞后时间设备(ALTA)技术可以确定T_(het)对溶质浓度的依赖性,并具有统计学意义。我们的研究结果表明,溶质诱导的T_(het)降低是任何固定浓度下等效熔点降低的两倍,对于小分子量溶质的均相成核实验报道了相同的因子。

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