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Hydrogen storage reaction over a ternary imide Li2Mg2N3H3

机译:三元酰亚胺Li2Mg2N3H3上的储氢反应

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摘要

The reaction details of hydrogen storage process of a ternary imide Li2Mg2N3H3 are elucidated for the first time. It is found that 1 mole of Li2Mg2N3H3 converts to a mixture of Mg(NH2)2-2LiH-MgNH on taking up 2 moles of H2, and that the presence of MgNH in the Mg(NH2)2-2LiH system not only alters the dehydrogenation thermodynamics but also improves the dehydrogenation kinetics.
机译:首次阐明了三元酰亚胺Li2Mg2N3H3的储氢过程的反应细节。发现1摩尔Li2Mg2N3H3在吸收2摩尔H2时会转化为Mg(NH2)2-2LiH-MgNH的混合物,并且Mg(NH2)2-2LiH系统中MgNH的存在不仅改变了脱氢热力学,但也改善了脱氢动力学。

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