Theoretical modeling on the kinetics of the arsenate-ester hydrolysis: implications to the stability of As-DNA

Arnost Mladek; Jiri Sponer; Bobby G. Sumpter

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Theoretical modeling on the kinetics of the arsenate-ester hydrolysis: implications to the stability of As-DNA

机译：砷酸酯水解反应动力学的理论模型：对As-DNA稳定性的影响

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Quantum chemical calculations reveal that neither steric hindrance nor less polar solvent medium is able to reduce the otherwise high hydrolysis rate of arsenate-esters. These results question the stability of As-DNA not only in aqueous but also in non-aqueous environments.

机译：量子化学计算表明，位阻或极性较小的溶剂介质均无法降低砷酸酯的其他高水解速率。这些结果不仅质疑As-DNA在水性环境中的稳定性，而且还质疑非水性环境中的稳定性。

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《Physical chemistry chemical physics: PCCP》 |2011年第23期|共3页
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Arnost Mladek; Jiri Sponer; Bobby G. Sumpter;
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Theoretical modeling on the kinetics of the arsenate-ester hydrolysis: implications to the stability of As-DNA

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