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Fatty acid droplet self-division driven by a chemical reaction

机译:由化学反应驱动的脂肪酸滴自分

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摘要

Division of a millimeter-sized and compartmentalized fatty acid droplet is triggered by a chemical pH clock reaction operating on the ten-second time scale. The autonomous pH change inside the compartment translates into the deprotonation of the fatty acid molecules, leading to a negative interfacial tension at the water-oil interface inside the droplet. This phenomenon induces the expansion of the droplet, which is followed by its division into daughter droplets governed by the Plateau-Rayleigh instability.
机译:毫米大小的分隔的脂肪酸小滴的分裂是由在十秒的时间刻度上进行的化学pH时钟反应触发的。隔室内的自主pH变化转化为脂肪酸分子的去质子化,从而在液滴内部的水-油界面处产生负界面张力。这种现象引起液滴的膨胀,随后将其分为受高原-瑞利不稳定性支配的子液滴。

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