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Photoemission properties of organic chain compounds

机译:有机链化合物的光发射特性

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In this work we extend our previous considerations of the spectral properties of quasi-one-dimensional bands using the G(0)W(0) approximation with the three-dimensional long-range Coulomb electron-electron interaction for the calculation of the one-particle spectral function to TTF-TCNQ. Represented in the model with two one-dimensional electron bands per donor and acceptor chains this compound has a dispersive low-energy collective mode due to the strong coupling between the plasmon and the dipolar mode, together with the mode at energies order of magnitude higher. Since the dispersion of the first mode spreads through the whole low-energy range from zero up to its longitudinal value, it is responsible for the absence of the low-energy quasi-particle and the appearance of broad dispersion at these energies, while the wide structure at higher energies is due to the dispersion of the second mode. Obtained spectral properties are in qualitative agreement with the ARPES data for TTF-TCNQ.
机译:在这项工作中,我们使用G(0)W(0)近似与三维长程库仑电子-电子相互作用来扩展对一维带的光谱特性的先前考虑,以计算一维TTF-TCNQ的粒子光谱函数。在该模型中,每个供体和受体链均具有两个一维电子带,该化合物由于等离激元与偶极子模式之间的强耦合以及能量数量级更高的模式而具有分散的低能集体模式。由于第一模式的色散分布在从零到其纵向值的整个低能量范围内,因此,这导致了低能量准粒子的缺乏以及在这些能量下出现了宽色散,而宽高能量下的结构是由于第二模式的分散。获得的光谱特性与TTF-TCNQ的ARPES数据在质量上一致。

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