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首页> 外文期刊>Physica, B. Condensed Matter >Corrosion resistance of NdFeB sintered magnets with intergranular addition of Cu_(60)Zn_(40) powders
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Corrosion resistance of NdFeB sintered magnets with intergranular addition of Cu_(60)Zn_(40) powders

机译:晶间添加Cu_(60)Zn_(40)粉末对NdFeB烧结磁体的耐腐蚀性

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摘要

Cu_(60)Zn_(40) powders, as grain boundary modifiers, were added into Nd_(28.2)Dy_(2.0)Fe_(bal)Al _(0.1)Nb_(0.2)Ga_(0.11)B_(0.96) sintered magnets to improve the corrosion resistance of magnets. The corrosion resistance of magnets was investigated by polarization curve measurements in 3.5 wt% NaCl and 3.0 wt% NaOH solutions. It was found that the Cu_(60)Zn _(40)-added magnets had more positive corrosion potential E _(corr) and much lower corrosion current density i_(corr) than the Cu_(60)Zn_(40)-free one in both solutions, indicating the improvement of the corrosion resistance by Cu_(60)Zn_(40) intergranular addition. Promotion of the electrochemical potential of the intergranular phase, formation of the Nd (Fe, Cu)_2 phase, the uniform distribution of the Nd-rich phase and increase of the magnet density were found to be responsible for the improvement of the corrosion resistance.
机译:将Cu_(60)Zn_(40)粉末作为晶界改性剂添加到Nd_(28.2)Dy_(2.0)Fe_(bal)Al _(0.1)Nb_(0.2)Ga_(0.11)B_(0.96)烧结磁体中提高磁体的耐腐蚀性。通过在3.5 wt%NaCl和3.0 wt%NaOH溶液中的极化曲线测量研究了磁体的耐腐蚀性。发现添加Cu_(60)Zn_(40)的磁体比不含Cu_(60)Zn_(40)的磁体具有更高的正腐蚀电位E _(corr),腐蚀电流密度i_(corr)低得多。两种溶液均表明,通过晶间添加Cu_(60)Zn_(40)可以提高耐蚀性。发现晶界相电化学势的提高,Nd(Fe,Cu)_2相的形成,富Nd相的均匀分布以及磁密度的增加是耐蚀性提高的原因。

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