New fluorene-substituted TTF derivatives as photofunctional materials

H. Fujiwara; K. Tsujimoto; Y. Sugishima; S. Takemoto; H. Matsuzaka

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New fluorene-substituted TTF derivatives as photofunctional materials

机译：新的芴取代的TTF衍生物作为光功能材料

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We have investigated photoinduced conductors and photoelectric conversion materials using new tetrathiafulvalene (TTF) derivatives containing a fluorescent part. In this study, we focused on new TTF molecules 1-3 in which a fluorene molecule was used as a fluorescent part and was connected to the TTF moiety through alkyl or alkene spacers. We discuss the synthesis, electrochemical properties, and optical properties of molecules 1-3. We also investigated the photoelectric conversion functionality by photoelectrochemical method using the thin films of molecules 1-3 that were spin-coated on ITO-coated glass substrate. We observed electric current generations that depend on the absorption spectra of thin films, suggesting that absorbed photons are converted to electric currents on the thin film/ITO electrode.

机译：我们已经研究了使用新的含有荧光部分的四硫富瓦烯（TTF）衍生物的光致导体和光电转换材料。在这项研究中，我们集中于新的TTF分子1-3，其中芴分子用作荧光部分，并通过烷基或烯烃间隔基连接到TTF部分。我们讨论了分子1-3的合成，电化学性质和光学性质。我们还使用旋涂在ITO涂层玻璃基板上的分子1-3的薄膜，通过光电化学方法研究了光电转换功能。我们观察到电流的产生取决于薄膜的吸收光谱，这表明吸收的光子在薄膜/ ITO电极上转换为电流。

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《Physica, B. Condensed Matter》 |2010年第11suppla期|共3页
作者
H. Fujiwara; K. Tsujimoto; Y. Sugishima; S. Takemoto; H. Matsuzaka;
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正文语种 eng
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Organic conductors; Photofunctional materials; Electrochemical properties; Optical properties; Photoelectric conversion;

机译：有机导体;光功能材料;电化学性能;光学性能;光电转换;

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1. New fluorene-substituted TTF derivatives as photofunctional materials [J] . H. Fujiwara, K. Tsujimoto, Y. Sugishima, Physica, B. Condensed Matter . 2010,第11Suppla期

机译：新的芴取代的TTF衍生物作为光功能材料
2. Organic Photofunctional Materials Composed of Azobenzene Derivatives: Liquid-solid Phase Transition in Multi Azobenzene Compounds with Partially Substituted Structures [J] . Haruhisa Akiyama, Masaru Yoshida, Hideyuki Kihara Journal of Photopolymer Science and Technology . 2014,第3期

机译：由偶氮苯衍生物组成的有机光功能材料：部分取代结构的多种偶氮苯化合物中的液相-固相转变
3. Organic Photofunctional Materials Composed of Azobenzene Derivatives: Liquid-solid Phase Transition in Multi Azobenzene Compounds with Partially Substituted Structures [J] . Haruhisa Akiyama, Masaru Yoshida, Hideyuki Kihara, Journal of Photopolymer Science and Technology . 2014,第3期

机译：由偶氮苯衍生物组成的有机光功能材料：部分取代结构的多种偶氮苯化合物中的液相-固相转变
4. NEW TETRATHIAFULVALENE (TTF) DERIVATIVES LINKED TO VARIOUS ACCEPTORS FOR ADVANCED MATERIALS [C] . A. GORGUES, D. KREHER, N. GAUTIER, NATO advanced research workshop on molecular low dimensional and nanostructured materials for advanced applicatons . 2002

机译：新的四叶酸瓦琳（TTF）衍生物与先进材料的各种受体相关联
5. SYNTHESES, STRUCTURES, AND PROPERTIES OF NEW MULTI-CHALCOGEN TTF DERIVATIVES, THEIR CHARGE-TRANSFER COMPLEXES AND ION-RADICAL SALTS [D] . 中野, 英之 1991

机译：新型多卤代TTF衍生物，其电荷转移复合物和离子根盐的合成，结构和性质
6. Synthesis of racemic and chiral BEDT-TTF derivatives possessing hydroxy groups and their achiral and chiral charge transfer complexes [O] . Sara Jane Krivickas, Chiho Hashimoto, Junya Yoshida, 2015

机译：具有羟基的外消旋和手性BEDT-TTF衍生物的合成及其非手性和手性电荷转移复合物
7. Organic Photofunctional Materials Composed of Azobenzene Derivatives: Liquid-solid Phase Transition in Multi Azobenzene Compounds with Partially Substituted Structures [O] . Haruhisa Akiyama, Masaru Yoshida, Hideyuki Kihara, 2014

机译：由偶氮苯衍生物组成的有机光功能材料：多偶氮苯化合物中的液固相变，部分取代的结构
8. Synthesis, Structure and Properties of BEDT-TTF Derivatives [R] . Nigrey, P. J. , Morosin, B. , Kwak, J. F. 1987

机译：BEDT-TTF衍生物的合成，结构与性质

New fluorene-substituted TTF derivatives as photofunctional materials

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