Regioselective synthesis of spiro-cyclopropanated 1-aminopyrrol-2-ones by Bi(OTf)(3)-catalyzed one-pot 'Mukaiyama-Michael addition/cyclization/ring-contraction' reactions of 1,2-bis(trimethylsilyloxy)cyclobutene with 1,2-diaza-1,3-butadienes

Attanas OA; Favi G; Giorgi G; Mantellini F; Karapetyan V; Langer P

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Regioselective synthesis of spiro-cyclopropanated 1-aminopyrrol-2-ones by Bi(OTf)(3)-catalyzed one-pot 'Mukaiyama-Michael addition/cyclization/ring-contraction' reactions of 1,2-bis(trimethylsilyloxy)cyclobutene with 1,2-diaza-1,3-butadienes

机译：Bi（OTf）（3）催化的1,2-双（三甲基甲硅烷氧基）环丁烯的一锅“ Mukaiyama-Michael加成/环化/环缩合”反应区域选择性合成螺环环丙烷化的1-氨基吡咯-2-酮1,2-二氮杂-1,3-丁二烯

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Unknown spiro-cyclopropanated 1-aminopyrrol-2-ones are regioselectively prepared in high yields by Bi(OTf)(3)-catalyzed one-pot 'Mukaiyama-Michael addition/cyclization/ring-contraction' reactions of 1,2-bis(trimethylsilyloxy)cyclobutene with 1,2-diaza-1,3-butadienes at room temperature.

机译：通过Bi（OTf）（3）催化的一锅'Mukaiyama-Michael加成/环化/环缩合'反应的1,2-bis（1）区域选择性高产率地制备未知的螺环-环丙烷化的1-aminopyrrol-2-ones。三甲基甲硅烷氧基）环丁烯与1,2-二氮杂-1,3-丁二烯在室温下。

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《Tetrahedron》 |2009年第28期|共6页
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Attanas OA; Favi G; Giorgi G; Mantellini F; Karapetyan V; Langer P;
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Unknown spiro-cyclopropanated; room temperature; regioselectively;

机译：未知螺旋环丙烷;室温;区域选择性;

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1. Regioselective synthesis of spiro-cyclopropanated 1-aminopyrrol-2-ones by Bi(OTf)(3)-catalyzed one-pot 'Mukaiyama-Michael addition/cyclization/ring-contraction' reactions of 1,2-bis(trimethylsilyloxy)cyclobutene with 1,2-diaza-1,3-butadienes [J] . Attanas OA, Favi G, Giorgi G, Tetrahedron . 2009,第28期

机译：Bi（OTf）（3）催化的1,2-双（三甲基甲硅烷氧基）环丁烯的一锅“ Mukaiyama-Michael加成/环化/环缩合”反应区域选择性合成螺环环丙烷化的1-氨基吡咯-2-酮1,2-二氮杂-1,3-丁二烯
2. Diversity-Oriented Synthesis of Functionalized 1-Aminopyrroles by Regioselective Zinc Chloride-Catalyzed, One-Pot 'Conjugate Addition/Cyclization' Reactions of 1,3-Bis(silyl enol ethers) with 1,2-Diaza-1,3-butadienes [J] . Vahuni Karapetyan, Satenik Mkrtchyan, Andreas Schmidt Advanced synthesis & catalysis . 2008,第9期

机译：区域选择性氯化锌催化的1,3-双（甲硅烷基烯醇醚）与1,2-二氮杂-1,3-丁二烯的一锅“共轭加成/环化”反应，以多样性为导向，合成功能化的1-氨基吡咯
3. Regioselective Synthesis of New 1-Aminopyrroles and 1-Amino-4,5,6,7-tetrahydroindoles by One-Pot ‘Conjugate Addition/Cyclization’ Reactions of 1,3-Bis(silyl enol ethers) with 1,2-Diaza-1,3-butadienes [J] . Andreas Schmidt, Vahuni Karapetyan, Orazio A. Attanasi, Synlett . 2007,第19期

机译：1,3-双（甲硅烷基烯醇醚）与1,2-二氮杂-的一锅“共轭加成/环化”反应区域选择性合成新的1-氨基吡咯和1-氨基-4,5,6,7-四氢吲哚1,3-丁二烯
4. One-pot Synthesis of Anthraquinones by Sc(OTf)3-catalyzed Tandem Reaction [C] . Yohei Toriyama, Yoko Yasuno, Tetsuro Shinada 日本化学会春季年会講演予稿集 . 2018

机译：SC（OTF）3催化串联反应的蒽醌合成蒽醌
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Bi(OTf)3– TfOH– and TMSOTf–Mediated One-Pot Epoxide Rearrangement Addition and Intramolecular Silyl-Modified Sakurai (ISMS) Cascade Toward Dihydropyrans: Comparison of Catalysts and Role of Bi(OTf)3 [O] . R. Frederick Lambert, Robert J. Hinkle, Stephen E. Ammann, -1

机译：Bi（OTF）3-TFOH-和TMSOTF介导的一锅环氧化物重排加法和分子内甲硅烷基改性的Sakurai（ISMS）级联朝向二氢吡喃：催化剂和Bi（OTF）3的作用比较
7. Highly Diastereoselective Synthesis of b-Carboxy-g-lactams and Their Ethyl Esters via Sc(OTf)3-Catalyzed Imino Mukaiyama-Aldol Type Reaction of 2,5-Bis(trimethylsilyloxy)furan with Imines [O] . -1

机译：通过SC（OTF）3催化的氨基Mukaiyama-Aldol型反应的2,5-双（三甲基甲硅烷基甲硅烷基）呋喃与亚胺的高度映选择性合成B-羧基-G-内酰胺和它们的乙酯
8. Phase Transfer Pd(O) Catalyzed Polymerization Reactions. 1. Synthesis of 1,2-(4,4'-Dialkoxyaryl)Acetylene Monomers and 1,4-Bis(2-(4',4''-Dialkoxyphenyl)Ethynyl)Benzene Derivatives by Phase Transfer Pd(O)/Cu(I) Catalyzed Coupling Reactions. [R] . Pugh, C., Percec, V. 1990

机译：相转移pd（O）催化的聚合反应。 1.相转移pd（O）/ Cu合成1,2-（4,4'-二烷氧基芳基）乙炔单体和1,4-双（2-（4'，4'-二烷氧基苯基）乙炔基）苯衍生物（I）催化的偶联反应。

Regioselective synthesis of spiro-cyclopropanated 1-aminopyrrol-2-ones by Bi(OTf)(3)-catalyzed one-pot 'Mukaiyama-Michael addition/cyclization/ring-contraction' reactions of 1,2-bis(trimethylsilyloxy)cyclobutene with 1,2-diaza-1,3-butadienes

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