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Phase diagrams of colloidal spheres with a constant zeta-potential

机译:ζ电势恒定的胶体球的相图

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We study suspensions of colloidal spheres with a constant zeta-potential within Poisson-Boltzmann theory, quantifying the discharging of the spheres with increasing colloid density and decreasing salt concentration. We use the calculated renormalized charge of the colloids to determine their pairwise effective screened-Coulomb repulsions. Bulk phase diagrams in the colloid concentration-salt concentration representation follow, for various zeta-potentials, by a mapping onto published fits of phase boundaries of point-Yukawa systems. Although the resulting phase diagrams do feature face-centered cubic and body-centered cubic phases, they are dominated by the (re-entrant) fluid phase due to the colloidal discharging with increasing colloid concentration and decreasing salt concentration.
机译:我们在Poisson-Boltzmann理论中研究了具有恒定zeta电位的胶体球的悬浮液,量化了随着胶体密度增加和盐浓度降低而产生的球体的放电。我们使用胶体的重新归一化电荷来确定其成对的有效筛选库仑斥力。对于各种ζ电位,胶体浓度-盐浓度表示中的本体相图通过映射到点-Yukawa系统的相界的已公布拟合上。尽管最终的相图确实具有面心立方相和体心立方相的特征,但由于胶体排放随着胶体浓度的增加和盐浓度的降低,它们被(凹腔)流体相主导。

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