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首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Configuration-specific kinetic theory applied to an ideal binary gas mixture
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Configuration-specific kinetic theory applied to an ideal binary gas mixture

机译:配置特定的动力学理论应用于理想的二元混合气

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This paper is the second in a two-part series dealing with the configuration-specific analyses for molecular collision events of hard, spherical molecules at thermal equilibrium. The first paper analyzed a single-component system, and the reader is referred to it for the fundamental concepts. In this paper, the expressions for the configuration-specific collision frequencies and the average line-of-centers collision angles and speeds are derived for an ideal binary gas mixture. The analyses show that the average line-of-centers quantities are all dependent upon the ratio of the masses of the two components, but not upon molecular size. Of course, the configuration-specific collision frequencies do depend on molecular size. The expression for the overall binary collision frequency is a simple sum of the configuration-specific collision frequencies and is identical to the conventional expression.
机译:本文是由两部分组成的系列文章的第二部分,该系列文章针对在热平衡下硬球形分子的分子碰撞事件进行了特定于结构的分析。第一篇论文分析了单组件系统,读者可以参考它的基本概念。在本文中,针对理想的二元混合气体,导出了特定于结构的碰撞频率,平均中心线碰撞角度和速度的表达式。分析表明,平均中心线量均取决于两种组分的质量比,而不取决于分子大小。当然,特定于配置的碰撞频率确实取决于分子大小。整体二进制碰撞频率的表达式是特定于配置的碰撞频率的简单总和,并且与常规表达式相同。

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