首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Dibenzylimidazolium halides: From complex molecular network in solid state to simple dimer in solution and in gas
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Dibenzylimidazolium halides: From complex molecular network in solid state to simple dimer in solution and in gas

机译:二苄基咪唑卤化物:从固态的复杂分子网络到溶液和气体中的简单二聚体

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摘要

1,3-Dibenzylimidazolium bromide has been synthesized and the nature of the interactions between cations and anions has been studied in the solid state, in solution and in the gas phase. The cohesion of the crystal is ensured by a combination of hydrogen bonds, and aromatic stacking interactions. In solution and in the gas phase, the supramolecular structural organization due to T-stacking is maintained to a great extent.
机译:合成了1,3-二苄基咪唑鎓溴化物,并研究了固态,溶液态和气相中阳离子与阴离子之间相互作用的性质。氢键和芳族堆积相互作用共同确保了晶体的凝聚力。在溶液中和在气相中,由于T堆积而导致的超分子结构组织得到了很大程度的维持。

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