Theoretical Study of Isomerization Mechanisms in Fluorinated Fullerene Derivatives

Stas M. Avdoshenko; Ilya N. Ioffe; Lev N. Sidorov

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Theoretical Study of Isomerization Mechanisms in Fluorinated Fullerene Derivatives

机译：氟化富勒烯衍生物的异构化机理的理论研究

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Various candidate processes that can effect rearrangement of the shell of addends are being discussed forC_(60)F_x and C_(60)(CF_3)_ycompounds. It is shown that isomerization of fluorofullerenes is catalyzed by other fullerenemolecules or organic donors, while in trifluoromethylated fullerenes such catalysis is inefficient. Theseobservations afford an explanation for important differences between fluorides and CF_3derivatives of C_(60)indistribution of products of their high-temperature syntheses.

机译：正在讨论可影响C_（60）F_x和C_（60）（CF_3）_ycompounds的各种候选过程，这些过程可能影响加成壳的重排。已表明氟富勒烯的异构化是由其他富勒烯分子或有机供体催化的，而在三氟甲基化富勒烯中，这种催化是无效的。这些观察结果解释了氟化物和C_（60）的CF_3衍生物在高温合成产物分布方面的重要区别。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2009年第40期|共6页
作者
Stas M. Avdoshenko; Ilya N. Ioffe; Lev N. Sidorov;
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Theoretical Study; Isomerization Mechanisms; Fluorinated Fullerene Derivatives;

机译：理论研究;异构化机理;含氟富勒烯衍生物;

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1. Theoretical Study of Isomerization Mechanisms in Fluorinated Fullerene Derivatives [J] . Stas M. Avdoshenko, Ilya N. Ioffe, Lev N. Sidorov The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2009,第40期

机译：氟化富勒烯衍生物的异构化机理的理论研究
2. Theoretical study on the reaction mechanism of the thermal cis-trans isomerization of fluorine-substituted azobenzene derivatives [J] . Liu Xiao-Mei, Jin Xing-Yi, Zhang Zhi-Xiang, RSC Advances . 2018,第21期

机译：氟取代的偶氮苯衍生物热顺式反式异构化反应机理的理论研究
3. Theoretical study on the reaction mechanism of the thermal cis–trans isomerization of fluorine-substituted azobenzene derivatives [J] . Xiao-Mei Liu, Xing-Yi Jin, Zhi-Xiang Zhang, RSC Advances . 2018,第21期

机译：氟代偶氮苯衍生物热顺-反异构化反应机理的理论研究
4. Isolation and characterisation of forty-eight fluorinated derivatives of 70fullerene: the ultimate hplc separation? [C] . Roger Taylor, Alaa K, Abdul-Sada, International symposium on recent advances in the chemistry and physics of fullerenes and related materials . 1999

机译：70富勒烯四十八氟化衍生物的分离与表征：最终的HPLC分离？
5. Crystallographic Structural Studies of Various Inorganic Compounds, Fullerene Derivatives, and Fullerene Cocrystals [D] . Claire, Faye Louisa 2013

机译：各种无机化合物，富勒烯衍生物和富勒烯共晶体的晶体学结构研究
6. Antioxidant Properties of Fullerene Derivatives Depend on Their Chemical Structure: A Study of Two Fullerene Derivatives on HELFs [O] . Vasilina Sergeeva, Olga Kraevaya, Elizaveta Ershova, 2019

机译：富勒烯衍生物的抗氧化性能取决于其化学结构：两种HEF上的富勒烯衍生物的研究
7. Step-Wise Computational Synthesis of Fullerene C60 derivatives. 1.Fluorinated Fullerenes C60F2k [O] . Sheka, Elena F. 2009

机译：富勒烯C60衍生物的逐步计算合成。 1.氟化富勒烯C60F2k
8. Theoretical and experimental investigations of fullerene derivatives: C60H2, C60H4, C 70H2 and C60(CH2)2 [R] . Jacobs, S J, Gillen, K T, Cahill, P A, 1993

机译：富勒烯衍生物的理论和实验研究：C60H2，C60H4，C70H2和C60（CH2）2

Theoretical Study of Isomerization Mechanisms in Fluorinated Fullerene Derivatives

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