Observation of the Hydrogen Migration in the Cation-Induced Fragmentation of the Pyridine Molecules

Wasowicz Tomasz J.; Pranszke Boguslaw

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Observation of the Hydrogen Migration in the Cation-Induced Fragmentation of the Pyridine Molecules

机译：氢在吡啶分子的阳离子诱导裂解中的迁移观察

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The ability to selectively control chemical reactions related to biology, combustion, and catalysis has recently attracted much attention. In particular, the hydrogen atom relocation may be used to manipulate bond-breaking and new bond-forming processes and may hold promise for far-reaching applications. Thus, the hydrogen atom migration preceding fragmentation of the gas-phase pyridine molecules by the H+, H-2(+), He+, and O+ impact has been studied experimentally in the energy range of 5-2000 eV using collision-induced luminescence spectroscopy. Formation of the excited NH(A(3)Pi) radicals was observed among the atomic and diatomic fragments. The structure of the pyridine molecule is lacking of the NH group, therefore observation of its A(3)Pi -> X-3 Sigma(-) emission bands is an evidence of the hydrogen atom relocation prior to the cation-induced fragmentation. The NH(A(3)Pi) emission yields indicate that formation of the NH radicals depends on the type of selected projectile and can be controlled by tuning its velocity. The plausible collisional mechanisms as well as fragmentation channels for NH formation in pyridine are discussed.

机译：选择性控制与生物学，燃烧和催化有关的化学反应的能力近来引起了很多关注。特别地，氢原子的重定位可用于操纵键断裂和新的键形成过程，并且对于广阔的应用前景可期。因此，使用碰撞诱导发光光谱在5-2000 eV的能量范围内，通过实验研究了气相吡啶分子被H +，H-2（+），He +和O +撞击破碎之前的氢原子迁移。。原子和双原子碎片之间观察到激发的NH（A（3）Pi）自由基的形成。吡啶分子的结构缺少NH基团，因此观察到其A（3）Pi-> X-3 Sigma（-）发射带是阳离子诱导断裂之前氢原子重新定位的证据。 NH（A（3）Pi）的发射量表明，NH自由基的形成取决于所选射弹的类型，可以通过调节其速度来控制。讨论了在吡啶中形成NH的可能的碰撞机理以及断裂通道。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2016年第7期|共8页
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Wasowicz Tomasz J.; Pranszke Boguslaw;
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1. Observation of the Hydrogen Migration in the Cation-Induced Fragmentation of the Pyridine Molecules [J] . Wasowicz Tomasz J., Pranszke Boguslaw The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2016,第7期

机译：氢在吡啶分子的阳离子诱导裂解中的迁移观察
2. Two [1,2,4-(Me_3C)_3C_5H_2]_2CeH Molecules are Involved in Hydrogenation of Pyridine to Piperidine as Shown by Experiments and Computations [J] . Lionel Perrin, Evan L. Werkema, Odile Eisenstein, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第13期

机译：实验和计算表明，有两个[1,2,4-（Me_3C）_3C_5H_2] _2CeH分子参与吡啶氢化为哌啶的过程
3. Two [1,2,4-(Me_3C)_3C_5H_2]_2CeH Molecules are Involved in Hydrogenation of Pyridine to Piperidine as Shown by Experiments and Computations [J] . Lionel Perrin, Evan L. Werkema, Odile Eisenstein, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第13期

机译：实验和计算表明，有两个[1,2,4-（Me_3C）_3C_5H_2] _2CeH分子参与吡啶氢化为哌啶的过程
4. Hydrogen migration during laser -induced two-body Coulomb explosion in polyatomic hydrocarbon molecules [C] . Conference on Lasers and Electro-Optics Europe . 2009

机译：激光期间的氢气迁移 - 在多原子烃分子中的双体库仑爆炸
5. EXCITATION FUNCTIONS AND ISOTOPE EFFECTS OF SOME SIMPLE ION-MOLECULE REACTIONS: CATION OF X PLUS HYDROGEN MOLECULE AND CATION OF HYDROGEN MOLECULE PLUS X, WHERE X IS A MOLECULE OF A GIVEN ELEMENT [D] . FENNELLY, PAUL FRANCIS. 1972

机译：一些简单的离子-分子反应的激发函数和同位素效应：X加上氢的阳离子和氢加上X的阳离子，X是给定元素的分子
6. Different Supramolecular Coordination Polymers of NN-di(pyrazin-2-yl)-pyridine-26-diamineNi(II) with Anions and Solvent Molecules as a Result of Hydrogen Bonding [O] . Gene-Hsiang Lee, Hsin-Ta Wang 2007

机译：由于氢键作用NN-二（吡嗪-2-基）-吡啶-26-二胺 Ni（II）与阴离子和溶剂分子的超分子配位聚合物
7. Studies on the Cleavage of Molecules by Catalytic Hydrogenation. XXX. The Effects of Thiophene and Pyridine on the Catalytic Hydrogenation of Aromatic Nitriles [O] . Tsutomu OKAZAWA, Masaaki HAYASHI, Kenichi WATANABE, 1961

机译：催化氢化分子切割研究。 XXX。噻吩和吡啶对芳香族腈催化加氢的影响

Observation of the Hydrogen Migration in the Cation-Induced Fragmentation of the Pyridine Molecules

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