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首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >Nanostructured 3D Sunflower-like Bismuth Doped BiOClxBr1-x Solid Solutions with Enhanced Visible Light Photocatalytic Activity as a Remarkably Efficient Technology for Water Purification
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Nanostructured 3D Sunflower-like Bismuth Doped BiOClxBr1-x Solid Solutions with Enhanced Visible Light Photocatalytic Activity as a Remarkably Efficient Technology for Water Purification

机译:纳米结构的3D向日葵状铋掺杂BiOClxBr1-x固溶体具有增强的可见光光催化活性,是一种非常有效的净水技术

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Following our report on the fabrication of BiOClxBr1-x (0 <= x <= 1) alloys, and via careful rational optimization and substantial tuning, we upgraded the previous photocatalytic system by means of a controlled doping with elemental bismuth particles. The latter leads to the formation of well-defined structures characterized by effective separation of electron hole pairs and more reductive photoexcited electrons. These advanced semiconductors, specifically heterojunctioned doped alloys, were synthesized via a simple soft chemical route at room temperature and used for demonstrating the enhanced and complete mineralization of recalcitrant organic contaminants in water such as toluene, benzene, chlorobenzene, xylene, terephthalic acid, and benzoquinone. The molecular photocatalytic mechanism of the above degradation processes was thoroughly elucidated.
机译:根据我们关于BiOClxBr1-x(0 <= x <= 1)合金制造的报告,并通过仔细的合理优化和实质性调整,我们通过对元素铋颗粒的受控掺杂来升级了先前的光催化系统。后者导致形成明确定义的结构,其特征在于有效分离电子空穴对和更多还原性光激发电子。这些先进的半导体,特别是异质结掺杂合金,是在室温下通过简单的软化学路线合成的,用于证明水中难降解有机污染物(例如甲苯,苯,氯苯,二甲苯,对苯二甲酸和苯醌)的增强和完全矿化作用。彻底阐明了上述降解过程的分子光催化机理。

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