Kinetic study of the photo-induced electron transfer reaction between ruthenium(II)complexes of 2,2'-bipyridine derivatives and methyl viologen.Effects of bulky substituents introduced onto 2,2'-bipyridinet

Taisuke Hamada; Sei-ichi Tanaka; Hiroaki Koga; Yumi Sakai; Shigeyoshi Sakaki

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Kinetic study of the photo-induced electron transfer reaction between ruthenium(II)complexes of 2,2'-bipyridine derivatives and methyl viologen.Effects of bulky substituents introduced onto 2,2'-bipyridinet

机译：2,2'-联吡啶衍生物钌（II）配合物与甲基紫精之间光诱导电子转移反应的动力学研究2,2'-联吡啶引入大取代基的影响

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Photo-induced electron transfer(ET)reactions form one of the important subjects of research over the last two decades.Since ruthcnium(II)tris(2,2'-bipyridine),[Ru(bpy)_3]~(2-),was successfully utilized for H_2 evolution from water,many studies have been carried out to elucidate the photochemical properties of [Ru(bpy)_3]~(2+).This complex is still one of the best photosensitizers because of its long-lived photo-excited state and significantly negative reduction potential at the excited state.Detailed knowledge of the photo-induced F.T reaction of this complex is necessary for making further developments of photochemical applications of this complex.

机译：光诱导电子转移（ET）反应是近二十年来的重要研究课题之一。自钌（II）tris（2,2'-联吡啶），[Ru（bpy）_3]〜（2-）已被成功用于从水中释放H_2的研究，已经进行了许多研究来阐明[Ru（bpy）_3]〜（2+）的光化学性质。由于其寿命长，该络合物仍然是最好的光敏剂之一。光激发态和在激发态时显着的负还原电位。对该复合物的光致FT反应的详细了解对于进一步开发该复合物的光化学应用是必要的。

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《Dalton transactions: An international journal of inorganic chemistry》 |2003年第4期|共7页
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Taisuke Hamada; Sei-ichi Tanaka; Hiroaki Koga; Yumi Sakai; Shigeyoshi Sakaki;
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1. Kinetic study of the photo-induced electron transfer reaction between ruthenium(II)complexes of 2,2'-bipyridine derivatives and methyl viologen.Effects of bulky substituents introduced onto 2,2'-bipyridinet [J] . Taisuke Hamada, Sei-ichi Tanaka, Hiroaki Koga, Dalton transactions: An international journal of inorganic chemistry . 2003,第4期

机译：2,2'-联吡啶衍生物钌（II）配合物与甲基紫精之间光诱导电子转移反应的动力学研究2,2'-联吡啶引入大取代基的影响
2. Photoinduced electron transfer reactions of ruthenium(II) complexes containing 2,2 '-bipyridine-4,4 '-dicarboxylic acid with phenols Steric and charge effects [J] . Swarnalatha K, Rajkumar E, Rajagopal S, Journal of Photochemistry and Photobiology, A. Chemistry . 2005,第1期

机译：含2,2'-联吡啶-4,4'-二羧酸的钌（II）配合物与酚的光诱导电子转移反应立体效应和电荷效应
3. KINETICS AND MECHANISM OF ELECTRON TRANSFER REACTIONS:OXIDATION OF HYPOPHOSPHORUS ACID BY PEROXODISULPHATE INDUCED BY IRRADIATION WITH VISIBLE LIGHT IN AN AQUEOUS SOLUTION CONTAINING tris(2,2-BIPYRIDINE)RUTHENIUM(II)ION [J] . S.BANSAL, N.K.SOM, C.L.KHANDELWAL Oxidation Communications . 2007,第4期

机译：电子传递反应的动力学和机理：可见光在含三（2,2-双联吡啶）钌（II）离子的水溶液中过氧化二氧过硫酸盐氧化过磷酸
4. Study of the electrochemiluminescence based on the reaction of allopurinol with Tris (2,2'-bipyridine) ruthenium (II) [C] . Yuwu Chi, JunLin Xie, Guonan Chen Sino-France Workshop on Surface Electrochemistry of Molecules of Biological Interest and Biosensor Application . 2001

机译：基于Allopurinol与Tris（2,2'-硼烷）钌（II）的反应研究电化学发光
5. Electron-transfer kinetics of copper(II/I) complexes with the ligands 1,10-phenanthroline, 2,2'-bipyridine and their derivatives in acetonitrile. [D] . McGillivary, Michael P. 2006

机译：铜（II / I）与配体1,10-菲咯啉，2,2'-联吡啶及其衍生物在乙腈中的电子转移动力学。
6. Ultrafast interligand electron transfer in cis-[Ru(4,4′-dicarboxylate-2,2′-bipyridine)2(NCS)2]4– and implications for electron injection limitations in dye sensitized solar cells [O] . Belinda Pettersson Rimgard, Jens Föhlinger, Jonas Petersson, 2020

机译：顺式-[Ru（4,4'-dicarboxylate-2,2'-bipyridine）2（NCS）2] 4–中超快速配体电子转移及其对染料敏化太阳能电池电子注入限制的影响
7. Light-induced Electron-transfer Reactions. 5. Kinetics of the Oxidation of Ethylenediaminetetraacetatocobaltate(II) Complexes by Peroxodisulfate Ion, Induced by Irradiation with Visible Light of Aqueous Solutions Containing Tris(2,2′-bipyridine)ruthenium(II) Ion [O] . Suzuko Nishida, Masaru Kimura 1987

机译：光诱导的电子转移反应。 5.通过过脱氧离子离子氧化乙二胺四乙酰钴钴酸钴酸酯（II）配合物的动力学，通过含有Tris（2,2'-吡啶）钌（II）离子的水溶液的可见光辐射诱导
8. Electron Transfer Quenching of the Luminescent Excited State of Tris(2,2'-Bipyridine)Ruthenium (II). A Flash Photolysis Relaxation Technique for Measuring the Rates of Very Rapid Electron Transfer Reactions. [R] . Bock, C. R., Meyer, T. J., Whitten, D. G. 1974

机译：三（2,2'-联吡啶）钌（II）发光激发态的电子转移猝灭。闪光光解弛豫技术测量快速电子转移反应速率。

Kinetic study of the photo-induced electron transfer reaction between ruthenium(II)complexes of 2,2'-bipyridine derivatives and methyl viologen.Effects of bulky substituents introduced onto 2,2'-bipyridinet

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