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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Stepwise replacement of nickel with cobalt ions in a [Ni_6] cluster
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Stepwise replacement of nickel with cobalt ions in a [Ni_6] cluster

机译:在[Ni_6]簇中用钴离子逐步替换镍

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摘要

Polydentate ligands were used to support planar methoxo-bridged {Ni _(6-x)Co_x} (x = 0, 1 or 2) clusters which were structurally characterized by single crystal analyses. The homometallic {Ni_6} complex displayed overall ferrimagnetic interactions between metal centres, and increasing the cobalt content led to a proportional increase in ac-response.
机译:多齿配体用于支撑平面甲氧基桥连的{Ni _(6-x)Co_x}(x = 0、1或2)团簇,其结构通过单晶分析来表征。同金属{Ni_6}配合物显示出金属中心之间的整体亚铁磁性相互作用,并且钴含量的增加导致交流响应的成比例增加。

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