A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

Li Z.-Y.; Dai J.-W.; Gagnon K.J.; Cai H.-L.; Yamamoto T.; Einaga Y.; Zhao H.-H.; Kanegawa S.; Sato O.; Dunbar K.R.; Xiong R.-G.

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A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

机译：呈现两步自旋转变和介电异常的中性Fe（iii）化合物

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The mononuclear ferric compound Fe(H-5-Cl-thsa-Me)(5-Cl-thsa-Me) ·H_2O (1) was synthesized and characterized using powder/single-crystal X-ray diffraction, M?ssbauer spectroscopy, differential scanning calorimetry (DSC), and magnetic susceptibility measurements. This photo-responsive compound shows reversible, two-step spin-crossover behaviour. Moreover, dielectric anomalies were observed during the spin transitions, demonstrating the multifunctional properties of compound 1.

机译：合成了单核三价铁化合物Fe（H-5-Cl-thsa-Me）（5-Cl-thsa-Me）·H_2O（1），并用粉末/单晶X射线衍射，Mssbauer光谱，差示扫描量热法（DSC）和磁化率测量。这种光敏化合物显示出可逆的两步自旋交叉行为。此外，在自旋跃迁期间观察到介电异常，证明了化合物1的多功能性质。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第41期|共4页
作者
Li Z.-Y.; Dai J.-W.; Gagnon K.J.; Cai H.-L.; Yamamoto T.; Einaga Y.; Zhao H.-H.; Kanegawa S.; Sato O.; Dunbar K.R.; Xiong R.-G.;
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neutral; exhibiting; anomalies;

机译：中性;展示;异常;

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1. A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies [J] . Li Z.-Y., Dai J.-W., Gagnon K.J., Dalton transactions: An international journal of inorganic chemistry . 2013,第41期

机译：呈现两步自旋转变和介电异常的中性Fe（iii）化合物
2. [Fe(nsal_2trien)]SCN, a New Two-Step Iron(III) Spin Crossover Compound, with Symmetry Breaking Spin-State Transition and an Intermediate Ordered State [J] . Vieira B.J.C., Coutinho J.T., Santos I.C., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第7期

机译：[Fe（nsal_2trien）] SCN，一种新型的两步式铁（III）自旋交换化合物，具有对称的破坏自旋态跃迁和中间有序态
3. Two bilayer organic-inorganic hybrid perovskite compounds exhibiting reversible phase transition and dielectric anomalies [J] . Jiang ZhenTao, Hao Yanhuan, Wang Hui, Journal of Solid State Chemistry . 2020,第期

机译：两种双层有机 - 无机杂交钙钛化合物，具有可逆相转变和介电异常
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A neutral Fe(iii) compound exhibiting a two-step spin transition and dielectric anomalies

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