A promising nonlinear optical material in the Mid-IR region: New results on synthesis, crystal structure and properties of noncentrosymmetric β-HgBrCl

Dang Y.; Meng X.; Jiang K.; Zhong C.; Chen X.; Qin J.

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A promising nonlinear optical material in the Mid-IR region: New results on synthesis, crystal structure and properties of noncentrosymmetric β-HgBrCl

机译：中红外区域中一种有希望的非线性光学材料：非中心对称β-HgBrCl的合成，晶体结构和性质的新结果

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This paper reports, for the first time, the nonlinear optical property of β-HgBrCl, which was synthesized by a reaction of Hg_2Cl _2 and Br_2 in EtOH. This reaction also gave α-HgBrCl. And the single crystal structures of both α- and β-HgBrCl are presented and compared. β-HgBrCl shows phase-matchable powder second harmonic generation (SHG) effect of about 2 times that of KH_2PO _4 (KDP). Its absorption edge in UV-vis spectrum locates at 366 nm, implying a wide band gap and therefore higher laser damage threshold. It also exhibits a relatively wide transparent window (from 0.4 to 20 μm) and relatively good thermal stability. This journal is

机译：本文首次报道了由Hg_2Cl _2和Br_2在EtOH中反应合成的β-HgBrCl的非线性光学性质。该反应也得到α-HgBrCl。给出并比较了α-和β-HgBrCl的单晶结构。 β-HgBrCl具有相匹配的粉末二次谐波（SHG）效应，约为KH_2PO _4（KDP）的2倍。它在紫外可见光谱中的吸收边缘位于366 nm，这意味着宽带隙，因此有更高的激光损伤阈值。它还具有相对较宽的透明窗口（0.4至20μm）和相对较好的热稳定性。这本日记是

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第27期|共5页
作者
Dang Y.; Meng X.; Jiang K.; Zhong C.; Chen X.; Qin J.;
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正文语种 eng
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Mid-IR; noncentrosymmetric; β-HgBrCl;

机译：中红外;非中心对称;β-HgBrCl;

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1. A promising nonlinear optical material in the Mid-IR region: New results on synthesis, crystal structure and properties of noncentrosymmetric β-HgBrCl [J] . Dang Y., Meng X., Jiang K., Dalton transactions: An international journal of inorganic chemistry . 2013,第27期

机译：中红外区域中一种有希望的非线性光学材料：非中心对称β-HgBrCl的合成，晶体结构和性质的新结果
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A promising nonlinear optical material in the Mid-IR region: New results on synthesis, crystal structure and properties of noncentrosymmetric β-HgBrCl

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