Metallopolymer formation using the (1R,2R)-N,N'-bis(pyridylmethylene) cyclohexane-1,2-diamine (BPID) ligand class

Vasudevan K.V.; Smythe N.C.; Scott B.L.; Gordon J.C.

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Metallopolymer formation using the (1R,2R)-N,N'-bis(pyridylmethylene) cyclohexane-1,2-diamine (BPID) ligand class

机译：使用（1R，2R）-N，N'-双（吡啶基亚甲基）环己烷-1,2-二胺（BPID）配体类别的金属聚合物形成

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The BPID ligand class is exploited as a scaffold for polymeric materials. Reaction of excess K or KH with the 2-pyridyl-BPID ligand results in the formation of a novel THF-bridged 1-D metallopolymer while the analogous reaction with the 4-pyridyl derivative results in a pyridyl-bridged 2-D metallopolymer.

机译：BPID配体类别被用作聚合物材料的支架。过量的K或KH与2-吡啶基-BPID配体的反应导致形成新的THF-桥连的1-D金属聚合物，而与4-吡啶基衍生物的类似反应导致吡啶基-桥连的2-D金属聚合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第14期|共4页
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Vasudevan K.V.; Smythe N.C.; Scott B.L.; Gordon J.C.;
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1. Metallopolymer formation using the (1R,2R)-N,N'-bis(pyridylmethylene) cyclohexane-1,2-diamine (BPID) ligand class [J] . Vasudevan K.V., Smythe N.C., Scott B.L., Dalton transactions: An international journal of inorganic chemistry . 2013,第14期

机译：使用（1R，2R）-N，N'-双（吡啶基亚甲基）环己烷-1,2-二胺（BPID）配体类别的金属聚合物形成
2. Asymmetric transfer hydrogenation of ketones in aqueous solution catalyzed by rhodium(III) complexes with C2-symmetric fluorene-ligands containing chiral (1R,2R)-cyclohexane-1,2-diamine [J] . Daniel Chávez, Gerardo Aguirre, Miguel Parra-hake, Journal of the Brazilian Chemical Society . 2010,第3期

机译：铑（III）与含手性（1R，2R）-环己烷-1,2-二胺的C2-对称芴-配体的配合物催化酮在水溶液中的不对称转移氢化
3. Asymmetric Transfer Hydrogenation of Ketones in Aqueous Solution Catalyzed by Rhodium(III) Complexes with C_2-Symmetric Fluorene-Ligands Containing Chiral (1R,2R)-Cyclohexane-1,2-diamine [J] . Ruben Montalvo-Gonzalez, Daniel Chavez, Gerardo Aguirre, Journal of the Brazilian Chemical Society . 2010,第3期

机译：铑（III）与含手性（1R，2R）-环己烷-1,2-二胺的C_2-对称芴配体的铑（III）配合物催化水溶液中酮的不对称转移加氢
4. Efficiency of bi-polarization and correlative radar-radiometer system for detection and classification of microwave anomalous formations of observed surfaces [C] . Hambaryan, A.K., Arakelyan, Geoscience and Remote Sensing Symposium Proceedings, 1998. IGARSS '98. 1998 IEEE International . 1998

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5. Synthesis of (1R,2R)-N1,N2-Dibenzylcyclohexane-1,2-diamine as an Auxiliary for a Stereoselective 1,4 Conjugate Addition Reaction; Construction of Polymer Bound (1R,2R)- 1,2-Cyclohexanediamine to evaluate the Solid-Phase Counterpart, and Methodology Development for Synthesis of Functionalized Oligothiophenes. [D] . Poorjahanshah, Homer. 2016

机译：（1R，2R）-N1，N2-二苄基环己烷-1，2-二胺作为立体选择性1，4共轭加成反应的助剂的合成；聚合物结合的（1R，2R）-1,2-环己二胺的构建以评价固相配对物，以及功能化寡聚噻吩的合成方法开发。
6. In vitro Antitumor Activity Intracellular Accumulation and DNA Adduct Formation of cis‐((1R 2R)‐12‐Cyclohexanediamine‐N N)bis(myristato) Platinum (II) Suspended in Lipiodol [O] . Shuichi Kishimoto, Kenji Miyazawa, Shoji Fukushima, 2000

机译：脂质体中悬浮的顺式（（1R2R）-12-环己二胺-NN）bis（myristato）铂（II）的体外抗肿瘤活性细胞内积累和DNA加合物形成
7. Transfer hydrogenation reduction of ketone catalyzed by Ru(II) and Rh(I) complexes with ligands derived from (1R,2R)-cyclohexane-1,2-diamine [O] . Norma Aidé Cortez, Celia Z. Flores-López, Ramón Rodríguez-Apodaca, 2005

机译：Ru（II）和Rh（I）配合物催化的酮与（1R，2R） - 环己烷-1,2-二胺配体的氢化还原反应

Metallopolymer formation using the (1R,2R)-N,N'-bis(pyridylmethylene) cyclohexane-1,2-diamine (BPID) ligand class

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