Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound

Al-Harbi A.; Rong Y.; Parkin G.

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Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound

机译：锌和th的三（2-吡啶基）甲基配合物的合成和结构表征：一类新的金属碳碳六烷和一价th烷基化合物

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Tris(2-pyridonyl)methanes may be synthesized via the reactions of the respective 2-pyridone with CHX_3 (X = Cl, Br) and K_2CO _3 in the presence of [Bu~n _4N]Br, followed by acid-catalyzed isomerization with camphorsulfonic acid. These compounds provide access to a new class of alkyl ligands that feature oxygen donors and are capable of forming metallacarbatranes and a monovalent thallium alkyl compound.

机译：三（2-吡啶基）甲烷可通过各自的2-吡啶酮与CHX_3（X = Cl，Br）和K_2CO _3在[Bu〜n _4N] Br的存在下反应，然后进行酸催化的异构化反应合成樟脑磺酸。这些化合物提供了新的一类具有氧供体特征的烷基配体，并能够形成金属碳环烷烃和一价alkyl烷基化合物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第39期|共5页
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Al-Harbi A.; Rong Y.; Parkin G.;
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Synthesis; characterization; metallacarbatranes;

机译：合成;表征;金属碳环戊烷;

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1. Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound [J] . Al-Harbi A., Rong Y., Parkin G. Dalton transactions: An international journal of inorganic chemistry . 2013,第39期

机译：锌和th的三（2-吡啶基）甲基配合物的合成和结构表征：一类新的金属碳碳六烷和一价th烷基化合物
2. Sterically demanding methyl tris(pyrazolyl)borate ligands: synthesis and characterization of thallium(I) complexes supported by [MeB(3-(t-Bu)Pz)(3)](-) and [MeB(3-(Mes)Pz)(3)](-) [J] . Dias HVR, Wang XY Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2004,第16期

机译：立体要求的三（吡唑基）硼酸甲酯配体：[MeB（3-（t-Bu）Pz）（3）]（-）和[MeB（3-（Mes）Pz）所支持的th（I）配合物的合成与表征）（3）]（-）
3. New class of oligonuclear platinum-thallium compounds with a direct metal-metal bond. 2. Structural characterization of the complexes [J] . Maliarik M., Glaser J., Sandstrom M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1998,第12期

机译：具有直接金属-金属键的新型寡核铂-compounds化合物。 2.配合物的结构表征
4. Structural and Electronic Properties of Thallium compounds [C] . Neetu Paliwal, Vipul Srivastava International Conference on Condensed Matter and Applied Physics . 2016

机译：铊化合物的结构和电子性质
5. New metal-organic chemistry of barium, an aqueous synthesis for volatile alkaline earth complexes, and synthesis and characterization of thallium-barium-calcium-copper-oxygen thin films by metal-organic chemical vapor deposition. [D] . Schulz, Douglas Lloyd. 1993

机译：钡的新金属有机化学，挥发性碱土金属配合物的水合成以及通过金属有机化学气相沉积法合成al-钡-钙-铜-氧薄膜。
6. Benzannulated Tris(2-mercapto-1-imidazolyl)hydroborato Ligands: Tetradentate κ4–S3H Binding and Access to Monomeric Monovalent Thallium in an S3 Coordination Environment [O] . Yi Rong, Joshua H. Palmer, Gerard Parkin -1

机译：苯甲酸酯化的Tris（2-巯基-1-咪唑基）氢硼酸盐配体：四齿κ4–S3H结合和在S3配位环境中获得单体单价hall。
7. Some Studies in Inorganic Complexes. XVI. Thallium(III) Complexes of 2-Aminomethylpyridine and 6-Methyl-2-aminomethylpyridine; Tris-(2,2'-bipyridyl)aluminium(III) Perchlorate [O] . GJ Sutton 1963

机译：无机复合物的一些研究。 XVI。 2-氨基甲基吡啶和6-甲基-2-氨基甲基吡啶的铊（III）配合物; Tris-（2,2'-双吡啶基）铝（III）高氯酸盐

Synthesis and structural characterization of tris(2-pyridonyl)methyl complexes of zinc and thallium: A new class of metallacarbatranes and a monovalent thallium alkyl compound

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