Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

Sergey Shuvaev; Valentina Utochnikova; ?ukasz Marciniak; Alexandra Freidzon; Ilya Sinev; Rik Van Deun; Ricardo O. Freire; Yan Zubavichus; Wolfgang Grünert; Natalia Kuzmina

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Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

机译：具有芳族邻磷酸化配体的镧系元素配合物：合成，结构阐明和光物理性质

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Lanthanide complexes LnL_3 (Ln = Sm, Eu, Tb, Dy, Tm, Yb, Lu) with aromatic o-phosphorylated ligands (HL~1 and HL~2) have been synthesized and identified. Their molecular structure was proposed on the basis of a new complex approach, including DFT calculations, Sparkle/PM3 modelling, EXAFS spectroscopy and luminescent probing. The photophysical properties of all of the complexes were investigated in detail to obtain a deeper insight into the energy transfer processes.

机译：已合成和鉴定了具有芳族邻磷酸化配体（HL〜1和HL〜2）的镧系元素配合物LnL_3（Ln = Sm，Eu，Tb，Dy，Tm，Yb，Lu）。在新的复杂方法的基础上提出了它们的分子结构，包括DFT计算，Sparkle / PM3建模，EXAFS光谱学和发光探测。详细研究了所有配合物的光物理性质，以更深入地了解能量转移过程。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第8期|共16页
作者
Sergey Shuvaev; Valentina Utochnikova; ?ukasz Marciniak; Alexandra Freidzon; Ilya Sinev; Rik Van Deun; Ricardo O. Freire; Yan Zubavichus; Wolfgang Grünert; Natalia Kuzmina;
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正文语种 eng
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Lanthanide; complexes; properties;

机译：镧系元素;络合物;性质;

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1. Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties [J] . Sergey Shuvaev, Valentina Utochnikova, ?ukasz Marciniak, Dalton transactions: An international journal of inorganic chemistry . 2014,第8期

机译：具有芳族邻磷酸化配体的镧系元素配合物：合成，结构阐明和光物理性质
2. Structure elucidation by sparkle/RM1, effect of lanthanide contraction and photophysical properties of lanthanide(III) trifluoroacetylacetonate complexes with 1,10-phenanthroline [J] . Ilmi Rashid, Iftikhar K. Journal of Photochemistry and Photobiology, A. Chemistry . 2016,第Null期

机译：通过火花/ RM1阐明结构，镧系元素的收缩效应以及镧系元素（III）与1,10-菲咯啉的三氟乙酰丙酮化物配合物的光物理性质
3. Synthesis, Crystal Structure, and Photophysical Properties of Novel (Monophthalocyaninato)lanthanide Complexes Stabilized by an Organometallic Tripodal Ligand [J] . Ke H, Wong WK, Wong WY, European journal of inorganic chemistry . 2009,第9期

机译：有机金属三脚架配体稳定的新型（单酞菁基）镧系元素配合物的合成，晶体结构和光物理性质
4. Synthesis and photophysical properties of lanthanide (III)complexes with a phosphate ligand having organic radicals [C] . SunaoShoji, Pedro Paulo Ferreira da Rosa, Yuichi Kitagawa 日本化学会春季年会 . 2020

机译：用有机自由基的磷酸镧（III）配合物的合成和光学性质
5. Fluoroalkyl and Fluoroaryl Fullerenes, Polycyclic Aromatic Hydrocarbons, and Copper(I) Complexes: Synthesis, Structure, Electrochemical, Photophysical, and Device Properties [D] . Reeves, Brian J. 2020

机译：氟代烷基和氟芳基富勒烯，多环芳烃和铜（I）配合物：合成，结构，电化学，光药和装置性能
6. Synthesis, Structures, and Photophysical Properties of Novel Four-Coordinate Cu(I) Complexes Supported by Chelating N-Heterocyclic Carbene Ligands [O] . Zhiqiang Wang, Xiaojuan Sun, Chen Xu, 1970

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7. Synthesis, characterization, photophysical properties of lanthanide complexes with flexible tripodal carboxylate ligands [O] . Chan CF, Li H, Seto C, 2013

机译：具有柔性三脚架羧酸酯配体的镧系元素配合物的合成，表征，光物理性质

Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

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