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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: Structural characterization of Pd(ii) complexes and their catalytic properties
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Abnormal carbenes derived from the 1,5-cycloaddition product between azides and alkynes: Structural characterization of Pd(ii) complexes and their catalytic properties

机译:从叠氮化物和炔烃之间的1,5-环加成产物衍生的异常碳烯:Pd(ii)配合物的结构表征及其催化性能

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摘要

The exclusive formation of the 1,5-cycloaddition product between azides and alkynes is taken advantage of in generating the first examples of abnormal carbenes from these precursors. This new route provides unprecedented post-functionalization possibilities for such abnormal carbenes.
机译:叠氮化物和炔烃之间1,5-环加成产物的排他形成是利用这些前体生成异常碳烯的第一个实例的优势。这种新途径为此类异常碳烯提供了前所未有的功能化后可能性。

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