'Auto-click' functionalization for diversified copper(I) and gold(I) NHCs

Houssein Ibrahim; Clémentine Gibard; Cédric Hesling; Régis Guillot; Laurent Morel; Arnaud Gautier; Federico Cisnetti

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'Auto-click' functionalization for diversified copper(I) and gold(I) NHCs

机译：多种铜（I）和金（I）NHC的“自动点击”功能

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Azide-tagged Cu~I-NHC reacts in an 'auto-click' process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting Cu~I complexes are amenable to further transmetallation to Au~I. The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties.

机译：叠氮化物标记的Cu〜NHC在“自动点击”过程中发生反应，以提供被带有各种取代基的1,2,3-三唑官能化的配合物。所得的Cu-I络合物适合于进一步的金属转移成Au-I。整个策略在温和的条件下进行，构成了具有生物相关部分的功能化金属-NHC的有效进入。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第19期|共9页
作者
Houssein Ibrahim; Clémentine Gibard; Cédric Hesling; Régis Guillot; Laurent Morel; Arnaud Gautier; Federico Cisnetti;
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正文语种 eng
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关键词
'Auto-click'; functionalization; gold(I) NHCs;

机译：“自动点击”;功能化;金（I）NHC;

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1. 'Auto-click' functionalization for diversified copper(I) and gold(I) NHCs [J] . Houssein Ibrahim, Clémentine Gibard, Cédric Hesling, Dalton transactions: An international journal of inorganic chemistry . 2014,第19期

机译：多种铜（I）和金（I）NHC的“自动点击”功能
2. Synthesis and Characterization of Gold(I) Complexes of Dibenzotropylidene-Functionalized NHC Ligands (Trop-NHCs) [J] . Brill Marcel, Collado Alba, Cordes David B., Organometallics . 2015,第1期

机译：二苯并亚苄基官能化NHC配体（Trop-NHCs）的金（I）配合物的合成和表征
3. From large 12-membered macrometallacycles to ionic (NHC)(2)M+Cl- type complexes of gold and silver by modulation of the N-substituent of amido-functionalized N-heterocyclic carbene (NHC) Ligands [J] . Samantaray MK, Pang K, Shaikh MM, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第10期

机译：通过调节酰胺基官能化的N-杂环卡宾（NHC）配体的N-取代基，从大型的12元大环化合物到金和银的离子（NHC）（2）M + Cl-型络合物
4. The study of adsorption of hydrogen onto copper and gold clusters by method of the density functional [C] . A A Kirsankin, N V Dohlikova, S Y Sarvadii International Youth Scientific Forum with International Participation New Materials . 2018

机译：密度函数方法对氢气吸附氢和金簇的研究
5. Functionalized organogold(I) complexes from base -promoted auration, copper(I)-catalyzed Huisgen 1,3-dipolar cycloaddition and Horner-Wadsworth-Emmons reactions and metallo-azadipyrromethene complexes for solar energy conversion and oxygen evolution. [D] . Gao, Lei. 2010

机译：来自碱促进的光催化，铜（I）催化的惠斯根1,3-偶极环加成反应和霍纳-沃兹沃思-埃蒙斯反应的功能化有机金（I）络合物以及用于太阳能转化和氧气释放的金属-氮杂二吡咯甲烷络合物。
6. N-Alkylation of functionalized amines with alcohols using a copper–gold mixed photocatalytic system [O] . Lyu-Ming Wang, Yuna Morioka, Kellie Jenkinson, -1

机译：铜-金混合光催化体系将官能化胺与醇进行N-烷基化
7. Synthesis and characterization of gold(I) complexes of dibenzotropylidene-functionalized NHC ligands (Trop-NHCs) [O] . Brill, Marcel, Collado-Martinez, Alba, Cordes, David Bradford, 2015

机译：二苯并亚苄基官能化的NHC配体（Trop-NHCs）金（I）配合物的合成和表征

'Auto-click' functionalization for diversified copper(I) and gold(I) NHCs

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