Cycloalkyl-based unsymmetrical unsaturated (U_2)-NHC ligands: flexibility and dissymmetry in ruthenium-catalysed olefin metathesis

Mathieu Rouen; Etienne Borré; Laura Falivene; Loic Toupet; Mika?l Berthod; Luigi Cavallo; Hélène Olivier-Bourbigou; Marc Mauduit

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Cycloalkyl-based unsymmetrical unsaturated (U_2)-NHC ligands: flexibility and dissymmetry in ruthenium-catalysed olefin metathesis

【24h】

Cycloalkyl-based unsymmetrical unsaturated (U_2)-NHC ligands: flexibility and dissymmetry in ruthenium-catalysed olefin metathesis

机译：基于环烷基的不对称不饱和（U_2）-NHC配体：钌催化的烯烃复分解中的柔性和不对称性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

Air-stable Ru-indenylidene and Hoveyda-type complexes bearing new unsymmetrical unsaturated N-heterocyclic carbene (U_2-NHC) ligands combining a mesityl unit and a flexible cycloalkyl moiety as N-substituents were synthesised. Structural features, chemical stabilities and catalytic profiles in olefin metathesis of this new library of cycloalkyl-based U_2-NHC Ru complexes were studied and compared with their unsymmetrical saturated NHC-Ru homologues as well as a set of commercially available Ru-catalysts bearing either symmetrical SIMes or IMes NHC ligands.

机译：合成了具有新的不对称不饱和N-杂环卡宾（U_2-NHC）配体的空气稳定的Ru-茚基和Hoveyda型配合物，该配体结合了1，2，3，4，5-三环烯单元和灵活的环烷基部分作为N-取代基。研究了这个新的基于环烷基的U_2-NHC Ru配合物库中烯烃复分解的结构特征，化学稳定性和催化分布，并与它们的不对称饱和NHC-Ru同系物以及一套市售的带有对称性的Ru催化剂进行了比较。 SIMes或IMes NHC配体。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2014年第19期|共6页
作者
Mathieu Rouen; Etienne Borré; Laura Falivene; Loic Toupet; Mika?l Berthod; Luigi Cavallo; Hélène Olivier-Bourbigou; Marc Mauduit;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
Cycloalkyl-based; (U_2)-NHC; dissymmetry;

机译：基于环烷基的;（U_2）-NHC;不对称;

相似文献

外文文献
中文文献
专利

1. Cycloalkyl-based unsymmetrical unsaturated (U_2)-NHC ligands: flexibility and dissymmetry in ruthenium-catalysed olefin metathesis [J] . Mathieu Rouen, Etienne Borré, Laura Falivene, Dalton transactions: An international journal of inorganic chemistry . 2014,第19期

机译：基于环烷基的不对称不饱和（U_2）-NHC配体：钌催化的烯烃复分解中的柔性和不对称性
2. [(NHC)(NHC_(ewg))RuCl_2(CHPh)] complexes with modified NHC_(ewg) ligands for efficient ring-closing metathesis leading to tetrasubstituted olefins [J] . Sashuk V., Peeck L.H., Plenio H. Chemistry: A European journal . 2010,第13期

机译：[（NHC）（NHC_（ewg））RuCl_2（CHPh）]配合物与修饰的NHC_（ewg）配体有效闭环易位，形成四取代烯烃
3. [(NHC)(NHC_ewg)RuCl₂(CHPh)] Complexes with Modified NHC_ewg Ligands for Efficient Ring-Closing Metathesis Leading to Tetrasubstituted Olefins† [J] . Volodymyr Sashuk Lars H. Peeck Herbert Plenio Chemistry - A European Journal . 2010,第13期

机译：[（NHC）（NHC _{ewg ）RuCl _{2 （CHPh）]配合物与修饰的NHC _{ewg 配体有效地闭合环，导致四取代烯烃†}}}
4. OLEFIN METATHESIS MEDIATED BY: - SCHIFF BASE Ru-ALKYLIDENES - Ru-ALKYLIDENES BEARING UNSYMMETRICAL NHC LIGANDS [C] . STIJN MONSAERT, NELE LEDOUX, BART ALLAERT, NATO Advanced Study Institute on Metathesis Chemistry: From Nanostructure Design to Synthesis of Advanced Materials . 2007

机译：烯烃复分解介导的： - 席克夫碱Ru-烷基 - Ru-烷基含有非对称NHC配体的Ru-烷基
5. Macrocyclic N-Heterocyclic Carbenes (NHC) for Size-Selective Nucleophilic Catalysis and Olefin Metathesis [D] . Zhang, Yutong. 2021

机译：大规模的N-杂环碳酸（NHC）用于大小选择性亲核催碱和烯烃复分解
6. Ruthenium-based olefin metathesis catalysts with monodentate unsymmetrical NHC ligands [O] . Veronica Paradiso, Chiara Costabile, Fabia Grisi 2018

机译：具有单齿不对称NHC配体的钌基烯烃复分解催化剂
7. Cycloalkyl-based unsymmetrical unsaturated (U2)-NHC ligands : flexibility and dissymmetry in ruthenium-catalysed olefin metathesis. [O] . Rouen, Mathieu, Borré, Etienne, Faliverne, Laura, 2014

机译：基于环烷基的不对称不饱和（U2）-NHC配体：钌催化的烯烃复分解中的柔性和不对称性。

Cycloalkyl-based unsymmetrical unsaturated (U_2)-NHC ligands: flexibility and dissymmetry in ruthenium-catalysed olefin metathesis

摘要

著录项

相似文献

相关主题

期刊订阅