Efficient removal of perchlorate ion from water by a water-insoluble M2L4 type compound

Mochizuki Masaru; Inoue Tatsunari; Yamanishi Katsunori; Koike Shiori; Kondo Mitsuru; Zhang Liang; Aoki Hiromi

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Efficient removal of perchlorate ion from water by a water-insoluble M2L4 type compound

机译：不溶于水的M2L4型化合物可有效去除水中的高氯酸根离子

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Reaction of CuSO4 center dot 5H(2)O with 1,3-bis(benzimidazol-1-ylmethyl)2,4,6- trimethylbenzene (m-bbitrb) provides a new positively charged M2L4 type molecule, [SO4 subset of Cu-2(m-bbitrb)(4)]SO4. This compound includes SO42- inside and outside the cationic cage. Despite this compound being insoluble in water, it shows highly efficient perchlorate removal activity from water by the exchange with SO42- outside the cage.

机译：CuSO4中心点5H（2）O与1,3-双（苯并咪唑-1-基甲基）2,4,6-三甲基苯（m-bbitrb）的反应提供了一个新的带正电的M2L4型分子，[Cu-的SO4子集2（m-bbitrb）（4）] SO4。该化合物在阳离子笼的内部和外部都包含SO42-。尽管该化合物不溶于水，但通过与笼外的SO42-交换显示出高效的高氯酸盐去除活性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第48期|共4页
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Mochizuki Masaru; Inoue Tatsunari; Yamanishi Katsunori; Koike Shiori; Kondo Mitsuru; Zhang Liang; Aoki Hiromi;
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1. Efficient removal of perchlorate ion from water by a water-insoluble M2L4 type compound [J] . Mochizuki Masaru, Inoue Tatsunari, Yamanishi Katsunori, Dalton transactions: An international journal of inorganic chemistry . 2014,第48期

机译：不溶于水的M2L4型化合物可有效去除水中的高氯酸根离子
2. Removal of Perchlorate and Tetrafluoroborate Anions from Aqueous Solutions by a Self-assembled Cu(II) Molecular Capsule System Using Water-insoluble Cu(II) Source [J] . Maiko Yamaguchi, Takeshi Hirakawa, Naoko Nishina Chemistry Letters . 2010,第11期

机译：自组装Cu（II）分子胶囊系统使用水不溶性Cu（II）源去除水溶液中的高氯酸根和四氟硼酸根阴离子
3. Simultaneous removal of perchlorate and energetic compounds in munitions wastewater by zero-valent iron and perchlorate-respiring bacteria [J] . SE CHANG AHN, BRIAN HUBBARD, DANIEL K. CHA, Journal of Environmental Science and Health . 2014,第5a6期

机译：零价铁和高氯酸盐呼吸细菌同时去除弹药废水中的高氯酸盐和高能化合物
4. Efficient Removal of Perchlorate from GroundwaterUsing Fixed-Bed Biological Treatment [C] . Jess Brown, Chance Lauderdale, Eberhard Morgenroth, International in situ and on-site bioremediation symposium . 2009

机译：使用固定床生物处理技术有效去除地下水中的高氯酸盐
5. Removal of perchlorate in ammunition wastewater by zero-valent iron and perchlorate respiring bacteria. [D] . Ahn, Se Chang. 2008

机译：零价铁和高氯酸盐呼吸细菌去除弹药废水中的高氯酸盐。
6. Rates of dissolution and biodegradation of water-insoluble organic compounds. [O] . J M Thomas, J R Yordy, J A Amador, 1986

机译：水不溶性有机化合物的溶解和生物降解速率。
7. Efficient removal of perchlorate ion from water by a water-insoluble M2L4type compound [O] . Mochizuki, Masaru, Inoue, Tatsunari, Yamanishi, Katsunori, 2014

机译：水不溶性M2L4型化合物可有效去除水中的高氯酸根离子
8. Rates of Dissolution and Biodegradation of Water-Insoluble Organic Compounds [R] . Thomas, J. M., Yordy, J. R., Amador, J. A., 1986

机译：水不溶性有机化合物的溶解和生物降解速率

Efficient removal of perchlorate ion from water by a water-insoluble M2L4 type compound

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