A 2,2 '-bipyridine coordination complex of [ICl2](+)

Shaw Andrew J. M.; Corbo Robert; Wilson David J. D.; Dutton Jason L.

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A 2,2 '-bipyridine coordination complex of [ICl2](+)

机译：[ICl2]（+）的2,2'-联吡啶配位复合物

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The formation of a new class of I(III) compound is reported; an N,N' chelated iodine cation ([bpy-ICl2](+); bpy = 2,2'-bipyridine). The complex is obtained as an [ICl4](-) salt and is formed via simple reaction of bpy with ICl3. The compound is relatively unstable, but may be stored as a solid and is shown to be competent in the oxidative chlorination of Au(I)-NHC complexes.

机译：据报道形成了新的一类I（III）化合物。 N，N'螯合的碘阳离子（[bpy-ICl2]（+）; bpy = 2,2'-联吡啶）。该络合物以[ICl4]（-）盐的形式获得，并且是通过bpy与ICl3的简单反应形成的。该化合物相对不稳定，但可以固体形式存储，并显示出对Au（I）-NHC络合物的氧化氯化作用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第34期|共5页
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Shaw Andrew J. M.; Corbo Robert; Wilson David J. D.; Dutton Jason L.;
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1. A 2,2 '-bipyridine coordination complex of [ICl2](+) [J] . Shaw Andrew J. M., Corbo Robert, Wilson David J. D., Dalton transactions: An international journal of inorganic chemistry . 2015,第34期

机译：[ICl2]（+）的2,2'-联吡啶配位复合物
2. Synthesis and coordination chemistry of the tetradentate ligands 6,6'-bis(3-pyrazolyl)-2,2'-bipyridine and 6,6'-bis(2-hydroxyphenyl)2,2'-bipyridine: intramolecular hydrogen-bonding in complexes of Cu(II), and a dinuclear double helicate with Ag(I) [J] . Samantha M. Couchman, John C. Jeffery, Michael D. Ward Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 1999,第20期

机译：四齿配体6,6'-双（3-吡唑基）-2,2'-联吡啶和6,6'-双（2-羟苯基）2,2'-联吡啶的合成和配位化学：分子内氢键Cu（II）的配合物，以及与Ag（I）的双核双螺旋
3. Coordination Chemistry of 2,2 '-Bipyridyl- and 2,2 ':6 ',2 ''-Terpyridyl-Substituted BEDT-TTFs: Formation of a Supramolecular Capsule Motif by the Iron(II) Tris Complex of 2,2 '-Bipyridine-4-thiomethyl-BEDT-TTF [J] . Wang Qiang, Martin Lee, Blake Alexander J., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2016,第17期

机译：2,2'-联吡啶-和2,2'：6'，2''-三联吡啶取代的BEDT-TTF的配位化学：由2,2'-的铁（II）Tris络合物形成超分子胶囊基序Bipyridine-4-thiomethyl-BEDT-TTF
4. Synthesis, Structures and Properties of Two New Three-dimensional Ce(lll) Coordination Polymers with 2,2'-bipyridine-4,4'-dicarboxylic Acid [C] . Ruiping Zheng, Huiyuan Chen, Junjie He International Conference on Advanced Engineering Materials and Technology . 2013

机译：两种新三维Ce（LLL）配位聚合物的合成，结构和性质用2,2'-硼烷-4,4'-二羧酸
5. A study of the lifetime of tris(2,2'-bipyridine)ruthenium (II) coordination complexes under pressure. [D] . Toomey, Richard Thomas. 2002

机译：三（2,2'-联吡啶）钌（II）配位化合物在压力下的寿命研究。
6. Coordination Chemistry of Ru(II) Complexes of an Asymmetric Bipyridine Analogue: Synergistic Effects of Supporting Ligand and Coordination Geometry on Reactivities [O] . Komi Akatsuka, Ryosuke Abe, Tsugiko Takase, 2020

机译：不对称联吡啶类似物Ru（II）配合物的配位化学：支持配体和配位几何对反应活性的协同作用
7. Coordination chemistry of 2,2’-bipyridyl- and 2,2’:6’,2”-terpyridyl-substituted BEDT-TTFs: formation of a supramolecular capsule motif by the iron(II) tris complex of 2,2’-bipyridine-4-thiomethyl-BEDT-TTF [O] . Wang Qiang, Martin Lee, Blake Alexander J., 2016

机译：2,2'-联吡啶-和2,2'：6'，2”-吡啶基取代的BETT-TTF的配位化学：由2,2'-联吡啶的铁（II）tris络合物形成超分子胶囊基序-4-硫代甲基-BEDT-TTF

A 2,2 '-bipyridine coordination complex of [ICl2](+)

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