Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

Harding David J.; Phonsri Wasinee; Harding Phimphaka; Murray Keith S.; Moubaraki Boujemaa; Jameson Guy N. L.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

【24h】

Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

机译：铁（III）络合物中突然的两步对称对称打破自旋交叉：[LS-HS]平稳期极宽

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

[Fe(qsal-Br)(2)]NO3 center dot 2MeOH is reported which undergoes abrupt two step symmetry breaking spin crossover, T-1/2(1st step) = 136 K and T-1/2(2nd step) = 232 K with a hysteresis of 16 K and 5 K, respectively, and an unprecedented [HS-LS] plateau of 96 K.

机译：报道[Fe（qsal-Br）（2）] NO3中心点2MeOH经历突然的两步对称，破坏了自旋交叉，T-1 / 2（第一步）= 136 K和T-1 / 2（第二步）= 232 K，分别具有16 K和5 K的磁滞，以及空前的96 K [HS-LS]平稳期。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2015年第34期|共4页
作者
Harding David J.; Phonsri Wasinee; Harding Phimphaka; Murray Keith S.; Moubaraki Boujemaa; Jameson Guy N. L.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau [J] . Harding David J., Phonsri Wasinee, Harding Phimphaka, Dalton transactions: An international journal of inorganic chemistry . 2015,第34期

机译：铁（III）络合物中突然的两步对称对称打破自旋交叉：[LS-HS]平稳期极宽
2. Solvent modified spin crossover in an iron(III) complex: phase changes and an exceptionally wide hysteresis [J] . Wasinee Phonsri, Phimphaka Harding, Lujia Liu, Chemical science . 2017,第5期

机译：铁（III）配合物中溶剂改性的自旋交联：相变和异常宽的磁滞
3. Symmetry Breaking and Two-Step Spin-Crossover Behavior in Two Cyano-Bridged Mixed-Valence {Fe-2(III)(mu-CN)(4)Fe-2(II)} Clusters [J] . Zheng Chunyang, Jia Shuwen, Dong Yubao, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019,第21期

机译：两个氰基桥接式混合价{Fe-2（III）（MU-CN）（4）FE-2（II）}簇中的对称性破碎和两步旋转交叉行为
4. Spin Crossover in Iron(ll) Complexes with Mixed Nitrogen-Sulfur Coordination: DFT Modeling [C] . S. I. Klokishner, O. S. Reu International Conference on Nanotechnologies and Biomedical Engineering . 2020

机译：用混合氮气协调的铁（LL）配合物中的旋转交叉：DFT建模
5. IRON AND RUTHENIUM COMPLEXES POSSESSING UNUSUAL ELECTRONIC PROPERTIES. PART I: SYNTHESIS AND SPIN STATE STUDIES OF GAMMA-SUBSTITUTED TRIS(BETA-DIKETONATO)IRON(III) COMPLEXES AND THEIR BETA-KETOIMINE ANALOGUES DERIVED FROM TRIETHYLENETETRAMINE. PART II: A DIRECT MEASUREMENT OF DYNAMIC SPIN INTERCONVERSION RATES IN THE SPIN EQUILIBRIUM PROTEIN FERRIC MYOGLOBIN HYDROXIDE. PART III: SYNTHESIS, PHOTOEMISSION, AND ELECTROCHEMICAL STUDIES OF. [D] . DOSE, ERIC VON. 1978

机译：铁和钌络合物具有异常的电子特性。第一部分：γ-取代的三（三乙酮）铁（III）配合物及其三乙胺丁胺类似物的β-酮亚胺类似物的合成和自旋态研究。第二部分：纺丝平衡蛋白三水合肌红蛋白中动态纺丝互变速率的直接测量。第三部分：的合成，光生化和电化学研究。
6. Solvent modified spin crossover in an iron(iii) complex: phase changes and an exceptionally wide hysteresis [O] . Wasinee Phonsri, Phimphaka Harding, Lujia Liu, 2017

机译：铁（iii）配合物中的溶剂改性的自旋交联：相变和异常宽的磁滞
7. Symmetry Breaking and Two-Step Spin-Crossover Behavior in Two Cyano-Bridged Mixed-Valence {FeIII2(-CN)4FeII2} Clusters [O] . -1

机译：两个氰网状混合价{Feiii2（-CN）4FeII2}集群中的对称性断裂和两步旋转交叉行为

Abrupt two-step and symmetry breaking spin crossover in an iron(III) complex: an exceptionally wide [LS-HS] plateau

摘要

著录项

相似文献

相关主题

期刊订阅