Observation of unusual slow-relaxation of the magnetisation in a Gd-EDTA chelate

Holmberg Rebecca J.; Le Tuan Anh Ho; Ungur Liviu; Korobkov Ilia; Chibotaru Liviu F.; Murugesu Muralee

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Observation of unusual slow-relaxation of the magnetisation in a Gd-EDTA chelate

机译：观察到Gd-EDTA螯合物中磁化的异常缓慢弛豫

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A Gadolinium EDTA chelate displays characteristic isotropic behaviour common of Gd-III complexes under zero applied magnetic field, and anisotropic behaviour arising from dipolar coupling and weak spin-phonon coupling under an applied magnetic field. This surprising magnetic behaviour for Gd-III is investigated using SQUID magnetometry and rationalized through theoretical calculations.

机译：EDTA螯合物在零磁场作用下表现出Gd-III配合物共有的特征各向同性行为，以及在磁场作用下由偶极耦合和弱自旋声子耦合引起的各向异性行为。使用SQUID磁力计研究了Gd-III的这种令人惊讶的磁行为，并通过理论计算对其进行了合理化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第47期|共5页
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Holmberg Rebecca J.; Le Tuan Anh Ho; Ungur Liviu; Korobkov Ilia; Chibotaru Liviu F.; Murugesu Muralee;
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机译：观察到Gd-EDTA螯合物中磁化的异常缓慢弛豫
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Observation of unusual slow-relaxation of the magnetisation in a Gd-EDTA chelate

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