The synthesis of heteroleptic phosphines

Kendall Alexander J.; Tyler David R.

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The synthesis of heteroleptic phosphines

机译：杂合膦的合成

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Heteroleptic phosphines (R2PR1) are a class of essential ligands for inorganic and organometallic chemistry. However, the syntheses of these phosphines are often fraught with laborious synthetic hurdles. Consequently, a renewed interest in innovative synthetic methods to access heteroleptic phosphines is emerging. This Perspective presents an overview of modern synthetic approaches to heteroleptic phosphines as well as a discussion of the strengths and limitations of these synthetic methods. A major emphasis is placed on simple and direct routes to phosphines and significant synthetic innovations for P-C bond-forming reactions.

机译：杂多膦（R2PR1）是无机和有机金属化学的一类重要配体。然而，这些膦的合成常常充满费力的合成障碍。因此，人们对创新的合成方法产生了新的兴趣，以使用杂合膦。本“观点”概述了杂合膦的现代合成方法，并讨论了这些合成方法的优缺点。主要重点放在简单直接的膦路线和用于P-C键形成反应的重大合成创新上。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第28期|共11页
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Kendall Alexander J.; Tyler David R.;
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The synthesis of heteroleptic phosphines

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