In situ synthesized 3D heterometallic metal-organic framework (MOF) as a high-energy-density material shows high heat of detonation, good thermostability and insensitivity

Feng Yaya; Liu Xiangyu; Duan Linqiang; Yang Qi; Wei Qing; Xie Gang; Chen Sanping; Yang Xuwu; Gao Shengli

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >In situ synthesized 3D heterometallic metal-organic framework (MOF) as a high-energy-density material shows high heat of detonation, good thermostability and insensitivity

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In situ synthesized 3D heterometallic metal-organic framework (MOF) as a high-energy-density material shows high heat of detonation, good thermostability and insensitivity

机译：作为高能量密度材料的原位合成3D杂金属金属有机骨架（MOF）显示出高的爆轰热，良好的热稳定性和不敏感性

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A reticular 3D heterometallic metal-organic framework (MOF), [Cu4Na(Mtta)(5)(CH3CN)](n) (1) (N% = 40.08%), has been synthesized, using a 5-methyl tetrazole (Mtta) ligand formed from acetonitrile and azide, through in situ synthesis and structurally characterized by X-ray single crystal diffraction. The fluorescence spectra demonstrate that 1 undergoes an interesting structural transformation in aqueous solution, yielding the compound [Cu4Na(Mtta)(5)H2O](n) (1a) as confirmed by H-1 NMR, IR and PXRD. Thermoanalysis showed that 1 possesses excellent thermostability up to 335 degrees C. The calculated detonation properties and the sensitivity test illustrate that compound 1 could be used as a potential explosive. In addition, the non-isothermal kinetics for 1 were studied using the Kissinger and Ozawa-Doyle methods. The enthalpy of formation was obtained from the determination of the constant-volume combustion energy.

机译：使用5甲基四唑（Mtta）合成了网状3D杂金属金属有机骨架（MOF）[Cu4Na（Mtta）（5）（CH3CN）]（n）（1）（N％= 40.08％））由乙腈和叠氮化物形成的配体，通过原位合成并通过X射线单晶衍射进行结构表征。荧光光谱表明1在水溶液中进行了有趣的结构转变，生成化合物[Cu4Na（Mtta）（5）H2O]（n）（1a），经H-1 NMR，IR和PXRD证实。热分析表明，1在高达335℃的温度下具有出色的热稳定性。计算的爆震性能和敏感性测试表明，化合物1可用作潜在的炸药。此外，使用Kissinger和Ozawa-Doyle方法研究了1的非等温动力学。通过确定恒定体积的燃烧能获得形成焓。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第5期|共7页
作者
Feng Yaya; Liu Xiangyu; Duan Linqiang; Yang Qi; Wei Qing; Xie Gang; Chen Sanping; Yang Xuwu; Gao Shengli;
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1. In situ synthesized 3D heterometallic metal-organic framework (MOF) as a high-energy-density material shows high heat of detonation, good thermostability and insensitivity [J] . Feng Yaya, Liu Xiangyu, Duan Linqiang, Dalton transactions: An international journal of inorganic chemistry . 2015,第5期

机译：作为高能量密度材料的原位合成3D杂金属金属有机骨架（MOF）显示出高的爆轰热，良好的热稳定性和不敏感性
2. Superior Thermostability, Good Detonation Properties, Insensitivity, and the Effect on the Thermal Decomposition of Ammonium Perchlorate for a New Solvent-Free 3D Energetic PbII-MOF [J] . Qi Yang, Guoli Yang, Wendou Zhang, Chemistry: A European journal . 2017,第38期

机译：优异的热稳定性，良好的爆轰性能，不敏感性，对新溶剂3D能量PBII-MOF进行高氯酸铵热分解的影响
3. In situ growth of metal-organic frameworks (MOFs) on the surface of other MOFs: a new strategy for constructing magnetic resonance/optical dual mode imaging materials [J] . Gao Xuechuan, Ji Guanfeng, Cui Ruixue, Dalton transactions: An international journal of inorganic chemistry . 2017,第40期

机译：在其他MOF的表面上的金属 - 有机框架（MOF）的原位生长：构造磁共振/光学双模成像材料的新策略
4. SYSTEMATIC STRATEGY TO SYNTHESIZE PHOTOACTIVE TITANIUM METAL-ORGANIC FRAMEWORKS (MOFS) [C] . Lanfang Zou, Dawei Feng, Tian-Fu Liu ACS National Meeting Exhibition . 2015

机译：合成光活性钛金属 - 有机框架（MOF）的系统策略
5. Synthesis, characterization, and catalytic performance of metal-organic frameworks (MOFs) and MOF-templated materials [D] . McNamara, Nicholas Dennis 2015

机译：金属有机骨架（MOF）和MOF模板材料的合成，表征和催化性能
6. Multifunctional Supramolecular Hybrid Materials Constructed from Hierarchical Self-Ordering of In Situ Generated Metal-Organic Framework (MOF) Nanoparticles [O] . Abhijeet K Chaudhari, Intaek Han, Jin-Chong Tan -1

机译：从原位生成的金属有机骨架（MOF）纳米粒子的分层自排序构造的多功能超分子杂化材料。
7. Supramolecular Materials: Multifunctional Supramolecular Hybrid Materials Constructed from Hierarchical Self-Ordering of In Situ Generated Metal-Organic Framework (MOF) Nanoparticles (Adv. Mater. 30/2015) [O] . Abhijeet K. Chaudhari, Intaek Han, Jin-Chong Tan 2015

机译：超分子材料：多功能超分子混合材料，由原位生成的金属 - 有机骨架（MOF）纳米颗粒（ADV。Mater。30/2015）构建自分层自动排序。

In situ synthesized 3D heterometallic metal-organic framework (MOF) as a high-energy-density material shows high heat of detonation, good thermostability and insensitivity

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