Partial oxidation of light alkanes by periodate and chloride salts

Kalman Steven E.; Munz Dominik; Fortman George C.; Boaz Nicholas C.; Groves John T.; Gunnoe T. Brent

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Partial oxidation of light alkanes by periodate and chloride salts

机译：高碘酸盐和氯化物盐会部分氧化轻质烷烃

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The efficient and selective partial oxidation of light alkanes using potassium periodate and potassium chloride is reported. Yields of methane functionalization in trifluoroacetic acid reach >40% with high selectivity for methyl trifluoroacetate. Periodate and chloride also functionalize ethane and propane in good yields (>20%).

机译：报道了使用高碘酸钾和氯化钾对轻烷烃进行有效和选择性的部分氧化。在三氟乙酸中甲烷官能化的产率达到> 40％，并且对三氟乙酸甲酯具有高选择性。高碘酸盐和氯化物还可以使乙烷和丙烷高收率（> 20％）官能化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第12期|共5页
作者
Kalman Steven E.; Munz Dominik; Fortman George C.; Boaz Nicholas C.; Groves John T.; Gunnoe T. Brent;
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1. Partial oxidation of light alkanes by periodate and chloride salts [J] . Kalman Steven E., Munz Dominik, Fortman George C., Dalton transactions: An international journal of inorganic chemistry . 2015,第12期

机译：高碘酸盐和氯化物盐会部分氧化轻质烷烃
2. Selective Photo-Oxygenation of Light Alkanes Using Iodine Oxides and Chloride [J] . Liebov Nichole S., Goldberg Jonathan M., Boaz Nicholas C., ChemCatChem . 2019,第20期

机译：使用碘氧化物和氯化物选择性光氧化光烷烃
3. Manganese(Ⅲ) porphyrin supported on multi-wall carbon nanotubes: A highly efficient and reusable biomimetic catalyst for oxidative decarboxylation of a-arylcarboxylic acids and oxidation of alkanes with sodium periodate [J] . Mehdi Araghi, Forough Bokaei Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2013,第Null期

机译：多壁碳纳米管上负载的锰（Ⅲ）卟啉：一种高效且可重复使用的仿生催化剂，用于α-芳基羧酸的氧化脱羧和高碘酸钠对烷烃的氧化
4. The lability of PMo polyoxo metallates in oxidative-reduction conditions of partial oxidation and oxidative dehydrogenation of alkanes [C] . G.U. Begimova, S.A. Tungatarova, T.S. Baizhumanova, Conference on Process Integration, Modelling and Optimisation for Energy Saving and Pollution Reduction . 2018

机译：PMO Polyoxo金属在烷化和氧化脱氢的氧化还原条件下的耐可性
5. Studies on Selective Partial Oxidation of Methane and Light Alkanes on Solid Metal Oxide Catalysts [D] . Wada, Kenji 1992

机译：固体金属氧化物催化剂上甲烷和轻烃的选择性部分氧化研究
6. Synthesis and characterisation of cobalt nickel and copper complexes with tripodal 4N ligands as novel catalysts for the homogeneous partial oxidation of alkanes [O] . Elisa Tordin, Manuela List, Uwe Monkowius, -1

机译：三脚架4N配体的钴镍和铜配合物的合成和表征作为烷烃均相部分氧化的新型催化剂
7. Selective Photo‐Oxygenation of Light Alkanes Using Iodine Oxides and Chloride [O] . Nichole S. Liebov, Jonathan M. Goldberg, Nicholas C. Boaz, 2019

机译：使用碘氧化物和氯化物选择性光氧化光烷烃

Partial oxidation of light alkanes by periodate and chloride salts

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