Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

Pagano Justin K.; Stelmach John P. W.; Waterman Rory

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Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

机译：需氧条件下钴催化氨硼烷脱氢偶联和转移加氢

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Two cobalt compounds, Cp*Co(CO)I-2 (1) and CpCo(CO)I-2 (2) (Cp* = eta(5)-C5Me5, Cp = eta(5)-C5H5), catalyze the dehydrogenation of ammonia borane under either anaerobic or aerobic conditions and are also effective hydrogenation catalysts for alkenes and alkynes using ammonia borane as a hydrogen source, also in the presence of air.

机译：两种钴化合物Cp * Co（CO）I-2（1）和CpCo（CO）I-2（2）（Cp * = eta（5）-C5Me5，Cp = eta（5）-C5H5）催化在厌氧或好氧条件下对氨硼烷进行脱氢，并且在空气存在下，使用氨硼烷作为氢源，也是用于烯烃和炔烃的有效加氢催化剂。

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《Dalton transactions: An international journal of inorganic chemistry》 |2015年第27期|共4页
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Pagano Justin K.; Stelmach John P. W.; Waterman Rory;
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1. Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions [J] . Pagano Justin K., Stelmach John P. W., Waterman Rory Dalton transactions: An international journal of inorganic chemistry . 2015,第27期

机译：需氧条件下钴催化氨硼烷脱氢偶联和转移加氢
2. Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane [J] . Kalviri Hassan A., Gaertner Felix, Ye Gang, Chemical science . 2015,第1期

机译：探索氨-硼烷脱氢偶联反应中的第二个脱氢步骤：关键中间体B-（环三氮杂硼烷基）胺-硼烷的表征和反应性
3. Probing the second dehydrogenation step in ammonia-borane dehydrocoupling: characterization and reactivity of the key intermediate, B-(cyclotriborazanyl)amine-borane [J] . Hassan A. Kalviri, Felix G?rtner, Gang Ye, Chemical science . 2015,第1期

机译：探索氨-硼烷脱氢偶联反应中的第二个脱氢步骤：关键中间体B-（环三氮杂硼烷基）胺-硼烷的表征和反应性
4. Ammonia Borane Dehydrogenation Always Generates Ammonia, How Much and How to Remove It? [C] . Ahmad Al-Kukhun, Hyun Tae Hwang, Arvind Varma AIChE annual meeting . 2010

机译：氨硼烷脱氢总是产生氨，多少氨以及如何去除氨？
5. Catalytic Dehydrogenation of Ammonia Borane-Polyvinylpyrrolidone Hydrogen Storage Composites with Different Molecular Weights [D] . Seemaladinne, Ramanjaneyulu. 2017

机译：不同分子量氨硼烷-聚乙烯基吡咯烷酮储氢复合材料的催化脱氢
6. Computational Prediction of Ammonia-Borane Dehydrocoupling and Transfer Hydrogenation of Ketones and Imines Catalyzed by SCS Nickel Pincer Complexes [O] . Bing Qiu, Wan Wang, Xinzheng Yang 1970

机译：SCS镍钳配合物催化的氨-硼烷脱氢偶联和酮和亚胺的转移加氢的计算预测
7. Cobalt-Catalyzed Ammonia Borane Dehydrogenation: Mechanistic Insight and Isolation of a Cobalt Hydride-Amidoborane Complex [O] . -1

机译：钴催化的氨基硼烷脱氢：机械洞察力和钴氢化物 - 酰胺络合物的分离
8. Chemical Hydrogen Storage Using Polyhedral Borane Anions and Aluminum-Ammonia-Borane Complexes. Final Report [R] . Hawthorne, M. F., Jalisatgi, S. S., Safronov, A. V., 2010

机译：使用多面体硼烷阴离子和铝 - 氨 - 硼烷配合物的化学氢储存。总结报告

Cobalt-catalyzed ammonia borane dehydrocoupling and transfer hydrogenation under aerobic conditions

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