Preparation and reactivity of a Ru(0) phosphino-carbene complex

Mosaferi Eliar; Pan Li; Wang Tongen; Sun Yunshan; Pranckevicius Conor; Stephan Douglas W.

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Preparation and reactivity of a Ru(0) phosphino-carbene complex

机译：Ru（0）膦-卡宾络合物的制备与反应

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The reaction of the phosphino-carbene MeNC3H2NPtBu2 with RuHCl(CO)(PPh3)(3) is shown to give facile access to the Ru(0) species (MeNC3H2NPtBu2) Ru(CO)(PPh3)(2) (1). This species undergoes oxidative addition of H-2 and silanes to give (MeNC3H2NPtBu2) RuH2(CO)(PPh3)(2) 4, (MeNC3H2NPtBu2) Ru H(SiRPh2)(CO)(PPh3) (R = Ph 5, H 6) and (MeNC3H2NPtBu2) RuH(PhSi(SCH2CH2)(2)O)(CO) (PPh3) 7.

机译：膦-卡宾MeNC3H2NPtBu2与RuHCl（CO）（PPh3）（3）的反应表明可以轻松访问Ru（0）物种（MeNC3H2NPtBu2）Ru（CO）（PPh3）（2）（1）。该物质经过H-2和硅烷的氧化加成，得到（MeNC3H2NPtBu2）RuH2（CO）（PPh3）（2）4，（MeNC3H2NPtBu2）Ru H（SiRPh2）（CO）（PPh3）（R = Ph 5，H 6 ）和（MeNC3H2NPtBu2）RuH（PhSi（SCH2CH2）（2）O）（CO）（PPh3）7。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第4期|共5页
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Mosaferi Eliar; Pan Li; Wang Tongen; Sun Yunshan; Pranckevicius Conor; Stephan Douglas W.;
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1. Preparation and reactivity of a Ru(0) phosphino-carbene complex [J] . Mosaferi Eliar, Pan Li, Wang Tongen, Dalton transactions: An international journal of inorganic chemistry . 2016,第4期

机译：Ru（0）膦-卡宾络合物的制备与反应
2. Preparation, characterization, and reactivity of azido complex containing a Tp(~tBuNC)(PPh _3)Ru fragment and ruthenium-catalyzed cycloaddition of organic azides with alkynes in organic and aqueous media [J] . Lo Y.-H., Wang T.-H., Lee C.-Y., Organometallics . 2012,第19期

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3. Preparation and reactivity of dihydrogen complexes [MX(#eta#~2-H_2)P_4]BF_4 (M = Ru or Os; X == halogenide or SEt~-; P = Phosphite) [J] . Gabriele Albertin, Stefano Antoniutti, Emilio Bordignon, Journal of the Chemical Society, Dalton Transactions. Inorganic Chemistry . 2000,第20期

机译：二氢配合物[MX（＃eta＃〜2-H_2）P_4] BF_4的制备和反应性（M = Ru或Os; X ==卤化物或SEt〜-; P =亚磷酸酯）
4. Preparation of Protic Amine Tethered Cp'Rh or Cp'Ru Complexes and Their Reactivity [C] . Masato Ito, Noriko Teiima, Masahiro Yamamura Symposium on Organometallic Chemistry . 2008

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5. The structure and reactivity of a series of high-valent oxo complexes of Ru and Mn: Ru(III)-mediated catalytic oxygenation of triphenylphosphine, characterization of binuclear Mn(III,III) and Mn(III,IV) dimers, and mononuclear iron(III) and iron(IV). [D] . Fackler, Nathanael L. P. 1997

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6. Coordination Chemistry of Ru(II) Complexes of an Asymmetric Bipyridine Analogue: Synergistic Effects of Supporting Ligand and Coordination Geometry on Reactivities [O] . Komi Akatsuka, Ryosuke Abe, Tsugiko Takase, 2020

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8. Synthesis and reactivity of Ru complexes with dibenzothiophene and hexahydrodibenzothiophene ligands: Models for catalytic hydrodesulfurization. [R] . Wang, C. M. J. 1990

机译：Ru配合物与二苯并噻吩和六氢二苯并噻吩配体的合成和反应性：催化加氢脱硫的模型。

Preparation and reactivity of a Ru(0) phosphino-carbene complex

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