Reactivity of aminophosphonic acids. Oxidative dephosphonylation of 1-aminoalkylphosphonic acids by aqueous halogens

Drabowicz Jozef; Jordan Frank; Kudzin Marcin H.; Kudzin Zbigniew H.; Stevens Christian V.; Urbaniak Pawel

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Reactivity of aminophosphonic acids. Oxidative dephosphonylation of 1-aminoalkylphosphonic acids by aqueous halogens

机译：氨基膦酸的反应性。 1-氨基烷基膦酸被卤素水溶液氧化脱膦酰化

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The reactions of 1-aminoalkylphosphonic acids with bromine-water, chlorine-water and iodine-water were investigated. The formation of phosphoric(v) acid, as a result of a halogen-promoted cleavage of the C-alpha-P bond, accompanied by nitrogen release, was observed. The dephosphonylation of 1-aminoalkylphosphonic acids was found to occur quantitatively. In the reactions of 1-aminoalkylphosphonic acids with other halogen-water reagents investigated by P-31 NMR, scission of the C-alpha-P bond was also observed, the reaction rates being comparable for bromine and chlorine, but much slower for iodine.

机译：研究了1-氨基烷基膦酸与溴水，氯水和碘水的反应。观察到由于卤素促进的C-α-P键裂解以及伴随着氮的释放，形成了磷酸（v）酸。发现1-氨基烷基膦酸的去膦酰化定量地发生。在通过P-31 NMR研究的1-氨基烷基膦酸与其他卤素水试剂的反应中，也观察到C-α-P键断裂，溴和氯的反应速率相当，而碘的反应速率慢得多。

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《Dalton transactions: An international journal of inorganic chemistry》 |2016年第5期|共10页
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Drabowicz Jozef; Jordan Frank; Kudzin Marcin H.; Kudzin Zbigniew H.; Stevens Christian V.; Urbaniak Pawel;
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1. Reactivity of aminophosphonic acids. Oxidative dephosphonylation of 1-aminoalkylphosphonic acids by aqueous halogens [J] . Drabowicz Jozef, Jordan Frank, Kudzin Marcin H., Dalton transactions: An international journal of inorganic chemistry . 2016,第5期

机译：氨基膦酸的反应性。 1-氨基烷基膦酸被卤素水溶液氧化脱膦酰化
2. Reactivity of aminophosphonic acids. 2. Stability in solutions of acids and bases [J] . Marcin H. Kudzin, Józef Drabowicz, Frank Jordan, Phosphorus, Sulfur, and Silicon and the Related Elements . 2019,第4a6期

机译：氨基磷酸的反应性。 2.酸和碱溶液中的稳定性
3. Direct oxidation of H-2 to H2O2 over Br and F-promoted Pd/Al2O3 in aqueous acidic medium: Influence of the concentration of Br and F and the method of incorporation of the two halogens in the catalyst on their beneficial synergetic effect on the net [J] . Choudhary VR, Jana P Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications . 2007,第0期

机译：在含水酸性介质中，Br和F促进的Pd / Al2O3上的H-2直接氧化为H2O2：Br和F的浓度以及催化剂中两种卤素的掺入方法对它们在网上的有益协同作用的影响
4. Recovery of Nicotinic Acid from Aqueous Solution using Reactive Extraction with Tri-n-Octyl Phosphine Oxide (TOPO) in Kerosene [C] . Sushil Kumar, Karan Gupta, B V Babu American Institute of Chemical Engineers Annual Meeting . 2009

机译：利用煤油中的三 - 辛基膦氧化膦（TOPO）与水溶液从水溶液中回收烟酸
5. A STUDY OF THE ACIDITY AND COMPLEXING PROPERTIES OF NITRILOTRIACETIC ACID N-OXIDE, ETHYLENE DIAMINETETRAACETIC ACID N,N'-DIOXIDE, DIPICOLINIC ACID N-OXIDE, AND 8-HYDROXYQUINOLINE-5-SULFONIC ACID N-OXIDE IN AQUEOUS SOLUTION. [D] . FREYER, LARRY EUGENE. 1975

机译：水溶液中亚硝基三乙酸N-氧化物，乙烯二胺基乙酸N，N'-二氧化物，双吡啶甲酸N-氧化物和8-羟基喹啉-5-磺酸磺酸的酸及其络合性能的研究。
6. Autoxidation of the fatty acids. 3. The oily products from elaidic and oleic acids. The formation of monoacyl derivatives of dihydroxystearic acid and of αβ-unsaturated keto acids [O] . G. W. Ellis 1950

机译：脂肪酸的自氧化。 3.亚麻油酸和油酸的油状产物。二羟基硬脂酸和αβ-不饱和酮酸的单酰基衍生物的形成
7. Reactivities and catalytic functions of heteropoly acids. XI. Effects of reduction of heteropoly acids on isobutene hydration in concentrated aqueous heteropoly acids. [O] . Atsushi AOSHIMA, Setsuo YAMAMATSU, Tatsuo YAMAGUCHI 1987

机译：杂多酸的反应性和催化功能。 XI。杂多酸还原对浓含水杂多酸中异丁烯水合的影响。
8. Kinetics of the Reactive Dissolution of the Nitrogen Oxides and Oxyacids in Aqueous Solution [R] . Schwartz, S. E., White, W. H. 1981

机译：氮氧化物和含氧酸在水溶液中反应溶解的动力学

Reactivity of aminophosphonic acids. Oxidative dephosphonylation of 1-aminoalkylphosphonic acids by aqueous halogens

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